Interaction of interfacial debonding and under-film corrosion propagation at the edge of the blistering area of epoxy coating

被引:3
作者
Li, Chao [1 ,2 ]
Gao, Jin [1 ,2 ]
Huang, Yunhua [1 ,2 ]
Zhang, Xin [3 ]
Li, Xiaogang [1 ,2 ]
机构
[1] Univ Sci & Technol Beijing, Inst Adv Mat & Technol, Natl Mat Corros & Protect Data Ctr, Beijing 100083, Peoples R China
[2] Univ Sci & Technol, Key Lab Corros & Protect, Minist Educ MOE, Beijing 100083, Peoples R China
[3] Univ Sci & Technol Beijing USTB Co Ltd, Testing Ctr, Beijing 100083, Peoples R China
关键词
Epoxy coating; LEIS; Blistering; Under-film corrosion; Interfacial debonding; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ORGANIC COATINGS; PROTECTION; MICROSCOPY; STEEL; DEGRADATION; MECHANISM; BEHAVIOR; SYSTEM;
D O I
10.1007/s11998-022-00680-4
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The blistering of epoxy coating and its evolution were investigated after being exposed to 3.5 wt% NaCl solution. The evolution of under-film corrosion could be divided into four stages according to the observation of the corrosion morphology and the distribution of corrosion products and elements. Corrosion propagation was related to the distribution of media at the edge of the blistering area. Local electrochemical impedance spectroscopy analysis revealed that local impedance mapping could help in predicting the direction of corrosion propagation. The interfacial debonding at the edge of the blistering area was a necessary condition for corrosion propagation.
引用
收藏
页码:457 / 468
页数:12
相关论文
共 48 条
[1]   In-Situ Monitoring of Local Corrosion Process of Scratched Epoxy Coated Carbon Steel in Simulated Pore Solution Containing Varying percentage of Chloride ions by Localized Electrochemical Impedance Spectroscopy [J].
Balusamy, T. ;
Nishimura, T. .
ELECTROCHIMICA ACTA, 2016, 199 :305-313
[2]   Active protection of Mg alloy by composite PEO coating loaded with corrosion inhibitors [J].
Chen, Yan ;
Lu, Xiaopeng ;
Lamaka, Sviatlana V. ;
Ju, Pengfei ;
Blawert, Carsten ;
Zhang, Tao ;
Wang, Fuhui ;
Zheludkevich, Mikhail L. .
APPLIED SURFACE SCIENCE, 2020, 504
[3]   An FT-IR investigation of epoxy coatings as a function of electrolyte composition [J].
Contu, F. ;
Fenzy, L. ;
Taylor, S. R. .
PROGRESS IN ORGANIC COATINGS, 2012, 75 (1-2) :92-96
[4]   Study of the coating/substrate interface by scanning acoustic microscopy - Cathodic disbonding of epoxy-polyamide lacquer from mild steel [J].
Crossen, JD ;
Sykes, JM ;
Zhai, T ;
Briggs, GAD .
FARADAY DISCUSSIONS, 1997, 107 :417-424
[5]   Relationship between ion transport and the failure behavior of epoxy resin coatings [J].
Dong, Yuhua ;
Zhou, Qiong .
CORROSION SCIENCE, 2014, 78 :22-28
[6]   Comparison of NMR and confocal Raman microscopy as coatings research tools [J].
Erich, SJF ;
Laven, J ;
Pel, L ;
Huinink, HP ;
Kopinga, K .
PROGRESS IN ORGANIC COATINGS, 2005, 52 (03) :210-216
[7]   In situ and dynamic observation of coating failure behavior [J].
Gao, Jin ;
Li, Chao ;
Feng, Hai-Xiang ;
Li, Xiao-Gang .
PROGRESS IN ORGANIC COATINGS, 2020, 138
[8]   Scanning Kelvin Probe Blister test measurements of adhesive delamination - Bridging the gap between experiment and theory [J].
Grothe, R. ;
Liu, Chen-Ni ;
Baumert, M. ;
Hesebeck, O. ;
Grundmeier, G. .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2017, 73 :8-15
[9]   Corrosion protection by organic coatings: electrochemical mechanism and novel methods of investigation [J].
Grundmeier, G ;
Schmidt, W ;
Stratmann, M .
ELECTROCHIMICA ACTA, 2000, 45 (15-16) :2515-2533
[10]   Insight into anticorrosion/antiwear behavior of inorganic-organic multilayer protection system composed of nitriding layer and epoxy coating with Ti3C2Tx MXene [J].
Yan, Han ;
Cai, Meng ;
Wang, Jiancheng ;
Zhang, Lin ;
Li, Hao ;
Li, Wen ;
Fan, Xiaoqiang ;
Zhu, Minhao .
APPLIED SURFACE SCIENCE, 2021, 536