Influence of the microstructure in the biodegradability process of eco-friendly materials based on polylactic acid and mango seed for food packaging to minimize microplastic generation

被引:0
作者
Lima, Edla Maria Bezerra [1 ,6 ]
Middea, Antonieta [2 ]
Reis, Fabio Silveira [3 ]
Mateus, Debora Nascimento [4 ]
de Amorim, Rodrigo Gomes [3 ]
Pereira, Ingrid Cristina Soares [1 ]
dos Santos, Natalia Rodrigues Rojas [1 ]
da Costa Mattos, Mariana [1 ]
da Silva Minguita, Adriana Paula [1 ]
dos Anjos, Marianna Ramos [1 ]
Neumann, Reiner [2 ]
Oliveira, Renata Nunes [3 ]
Tavares, Maria Ines Bruno [5 ]
机构
[1] Brazilian Agr Res Corp Embrapa Food Technol, Rio De Janeiro, Brazil
[2] CETEM, Ctr Mineral Technol, Rio De Janeiro, Brazil
[3] UFRRJ, Postgrad Program Chem Engn DEQ, Seropedica, Brazil
[4] State Univ West Zone, UEZO, Grad Polymers, Rio De Janeiro, Brazil
[5] Univ Fed Rio de Janeiro, Macromol Inst, Rio De Janeiro, Brazil
[6] Av Amer 29501, BR-23020470 Rio De Janeiro, RJ, Brazil
关键词
biocompatibility; biodegradable; biomaterials; biopolymers and renewable polymers; degradation; RAMAN-SPECTROSCOPY; MECHANICAL-PROPERTIES; STARCH CRYSTALLINITY; LACTIC-ACID; PLA; FILMS; CRYSTALLIZATION; BIOCOMPOSITES; NANOWHISKERS; SPECTRA;
D O I
10.1002/app.55449
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this research, mango parts (kernel and integument) were loaded into a polylactic acid (PLA) matrix by a casting process to develop biocomposite materials. These materials should present improved mechanical and thermal properties and have the potential to be used as environmentally friendly, biodegradable food packaging material with extended shelf life. For this purpose, the research was divided into two parts: step 1, ground materials of a certain particle size from a previous work1 and step 2, which are the materials from Step 1 ground again. The samples were characterized by x-ray diffraction, scanning electron microscopy (SEM), laser granulometry, texture tests, and thermal analysis. The difference between them was particle size distribution, impacting the materials' mechanical strength and degradation rate. Three biocomposites were made (PLA/kernel, PLA/integument, and PLA/kernel/integument) in both steps. SEM was used to observe the size distribution of the mango seed and sample morphology. In addition, resistance values increased with the addition of kernel or integument particles. Biocomposite biodegradability was also evaluated. Based on the results of this study, the biocomposites showed high mechanical properties and thermal stability, making them suitable for applications such as food packaging and structural components to help reduce environmental loads and microplastic generation. Overview of procedures for obtaining food packaging eco-friendly biocomposite materials showing that the material ground in a first study (Step1) was ground again (Step 2) and was used in the present work presenting excellent properties. image
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页数:19
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