A mesoporous Zr-based metal-organic framework driven by the assembly of an octatopic linker

被引：9

作者：

Ortin-Rubio, Borja ^{[1
,2
,3
]}

Perona-Bermejo, Cristina ^{[4
]}

Suarez del Pino, Jose A. ^{[1
,2
,3
]}

Carmona, Francisco J. J. ^{[4
]}

Gandara, Felipe ^{[5
]}

Navarro, Jorge A. R. ^{[4
]}

Juanhuix, Judith ^{[6
]}

Imaz, Inhar ^{[1
,2
,3
]}

Maspoch, Daniel ^{[1
,2
,3
,7
]}

机构：

[1] CSIC, Catalan Inst Nanosci & Nanotechnol ICN2, Campus UAB, Barcelona 08193, Spain

[2] Barcelona Inst Sci & Technol, Campus UAB, Barcelona 08193, Spain

[3] Univ Autonoma Barcelona, Dept Quim, Fac Ciencies, Bellaterra 08193, Spain

[4] Univ Granada, Dept Quim Inorgan, Ave Fuentenueva S-N, Granada 18071, Spain

[5] CSIC, Mat Sci Inst Madrid ICMM, Calle Sor Juana de la Ines Cruz 3, Madrid 28049, Spain

[6] ALBA Synchrotron, Cerdanyola Del Valles 08290, Barcelona, Spain

[7] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 50期

基金：

欧洲研究理事会;

关键词：

RETICULAR CHEMISTRY; CRYSTAL-STRUCTURES; ADSORPTION; CONSTRUCTION; DATABASE; DESIGN; NET; MOF;

D O I：

10.1039/d3cc01831h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zr-oxocluster and an 8-c organic linker. BCN-348 contains a minimal edge-transitive 3,4,8-c eps net, and combines mesoporosity with thermal and hydrolytic stability. Encouraging results from preliminary studies on its use as a catalyst for hydrolysis of a nerve-agent simulant suggest its potential as an agent for detoxification of chemical weapons and other pernicious compounds.

引用

页码：7803 / 7806

页数：4

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