A mesoporous Zr-based metal-organic framework driven by the assembly of an octatopic linker

被引：7
|
作者：
Ortin-Rubio, Borja [1 ,2 ,3 ]
Perona-Bermejo, Cristina [4 ]
Suarez del Pino, Jose A. [1 ,2 ,3 ]
Carmona, Francisco J. J. [4 ]
Gandara, Felipe [5 ]
Navarro, Jorge A. R. [4 ]
Juanhuix, Judith [6 ]
Imaz, Inhar [1 ,2 ,3 ]
Maspoch, Daniel [1 ,2 ,3 ,7 ]
机构：
[1] CSIC, Catalan Inst Nanosci & Nanotechnol ICN2, Campus UAB, Barcelona 08193, Spain
[2] Barcelona Inst Sci & Technol, Campus UAB, Barcelona 08193, Spain
[3] Univ Autonoma Barcelona, Dept Quim, Fac Ciencies, Bellaterra 08193, Spain
[4] Univ Granada, Dept Quim Inorgan, Ave Fuentenueva S-N, Granada 18071, Spain
[5] CSIC, Mat Sci Inst Madrid ICMM, Calle Sor Juana de la Ines Cruz 3, Madrid 28049, Spain
[6] ALBA Synchrotron, Cerdanyola Del Valles 08290, Barcelona, Spain
[7] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 50期
基金：
欧洲研究理事会;
关键词：
RETICULAR CHEMISTRY; CRYSTAL-STRUCTURES; ADSORPTION; CONSTRUCTION; DATABASE; DESIGN; NET; MOF;
D O I：
10.1039/d3cc01831h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zr-oxocluster and an 8-c organic linker. BCN-348 contains a minimal edge-transitive 3,4,8-c eps net, and combines mesoporosity with thermal and hydrolytic stability. Encouraging results from preliminary studies on its use as a catalyst for hydrolysis of a nerve-agent simulant suggest its potential as an agent for detoxification of chemical weapons and other pernicious compounds.
引用
收藏
页码：7803 / 7806
页数：4
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