A crowned manganese-based Schiff complex supported on nanocellulose as an efficient and sustainable heterogeneous catalyst for the oxidation of benzyl alcohols

被引：23

作者：

Maleki, Behrooz ^{[1
]}

Sandaroos, Reza ^{[2
]}

Naderi, Sanaz ^{[2
]}

Peiman, Sahar ^{[1
]}

机构：

[1] Univ Mazandaran, Fac Chem, Dept Organ Chem, Babolsar, Iran

[2] Univ Birjand, Fac Sci, Dept Chem, Birjand, Iran

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2023年 / 990卷

关键词：

Aerobic oxidation; Bis(imino)pyridine; Crown ether; Nano cellulose; SILK FIBROIN; SELECTIVE OXIDATION; CELLULOSE HYDROGEL; AEROBIC OXIDATION; NANOPARTICLES; EPOXIDATION; SCAFFOLD; OLEFINS; GREEN; POLYMERIZATION;

D O I：

10.1016/j.jorganchem.2023.122666

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this study, a Schiff- base- manganese complexes containing crown ether ring synthesized, immobilized on nanocellulose (MnL2@nanocellulose) and characterized by FT-IR, H -NMR, EDX, UV-Vis, microanalysis (CHN and ICP) and SEM. This catalyst was used for the oxidation of benzyl alcohols and its performance was compared with the analogue without crown ether (MnL 1 @nanocellulose). The results showed that MnL 2 @nanocellulose had much better catalytic activity despite the lower Mn content. (c) 2023 Elsevier B.V. All rights reserved.

引用

页数：12

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