Study of Lithium-Extraction Systems Based on Benzo-15-Crown-5 Ether and Alkylimidazolium-Based Ionic Liquid

被引：10
作者：
Bezdomnikov, Alexey A. A. [1 ]
Demina, Liudmila I. I. [1 ]
Kuz'mina, Lyudmila G. G. [2 ]
Kostikova, Galina V. V. [1 ]
Zhilov, Valeriy I. I. [1 ]
Tsivadze, Aslan Yu. [1 ]
机构：
[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Leninsky Pr 31-4, Moscow 119071, Russia
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninsky Pr 31, Moscow 119991, Russia
来源：
MOLECULES | 2023年 / 28卷 / 03期
关键词：
lithium extraction; lithium isotopes; benzo-15-crown-5; ether; complex synthesis; FTIR spectroscopy; X-RAY-DIFFRACTION; CONDUCTION PATHS; CROWN-ETHER; SEPARATION; COMPLEXES; ISOTOPES; STABILITY; BEHAVIOR;
D O I：
10.3390/molecules28030935
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The extraction of lithium from aqueous solutions of LiNTf2 and LiCl salts using benzo-15-crown-5 ether (B15C5) as an extractant in [C8mim][NTf2] ionic liquid was studied. The transition of the extractant into the aqueous phase and the distribution of Cl- ions during lithium extraction from LiCl solutions were determined. LiNTf2 complexes with B15C5 with different LiNTf2:B15C5 ratios were isolated for the first time and characterized via X-ray diffraction and IR spectroscopy. Differences in the extraction process of LiCl and LiNTf2 were determined via an infrared spectroscopic study of the extraction systems.
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页数：18
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共 38 条
[11]   Structural diversity in Lewis-base complexes of lithium triflamide [J].
Davidson, MG ;
Raithby, PR ;
Johnson, AL ;
Bolton, PD .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (18) :3445-3452
[12]   Effects of Side-Chain Substituents in Benzo-15-Crown-5 on Lithium Extraction [J].
Demin, S. V. ;
Shokurova, N. A. ;
Demina, L. I. ;
Kuz'mina, L. G. ;
Zhilov, V. I. ;
Tsivadze, A. Yu. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (01) :121-127
[13]   Lithium and boron isotope effects in extraction systems [J].
Demin, S. V. ;
Zhilov, V. I. ;
Tsivadze, A. Yu. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2015, 60 (05) :633-637
[14]   Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopy [J].
Demina, L. I. ;
Kuz'mina, L. G. ;
Demin, S. V. ;
Shokurova, N. A. ;
Zhilov, V. I. ;
Tsivadze, A. Yu. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2017, 62 (11) :1536-1543
[15]   OLEX2: a complete structure solution, refinement and analysis program [J].
Dolomanov, Oleg V. ;
Bourhis, Luc J. ;
Gildea, Richard J. ;
Howard, Judith A. K. ;
Puschmann, Horst .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341
[16]   Glyme-lithium bis(trifluoromethanesulfonyl)imide and glyme-lithium bis(perfluoroethanesulfonyl)imide phase behavior and solvate structures [J].
Henderson, WA ;
McKenna, F ;
Khan, MA ;
Brooks, NR ;
Young, VG ;
Frech, R .
CHEMISTRY OF MATERIALS, 2005, 17 (09) :2284-2289
[17]   Ionic Liquids in Asymmetric Synthesis: An Overall View from Reaction Media to Supported Ionic Liquid Catalysis [J].
Karimi, Babak ;
Tavakolian, Mina ;
Akbari, Maryam ;
Mansouri, Fariborz .
CHEMCATCHEM, 2018, 10 (15) :3173-3205
[18]   Behavior of Na and K in the extraction process of lithium isotope separation [J].
Kostikova, G. V. ;
Maltseva, I. E. ;
Krasnova, O. G. ;
Shokurova, N. A. ;
Zhilov, V. I. .
RUSSIAN CHEMICAL BULLETIN, 2018, 67 (12) :2188-2190
[19]   Study of the Structure of Lithium Thiocyanate Complexes with Benzo-15-Crown-5 by X-ray Diffraction and IR Spectroscopy [J].
Kuz'mina, L. G. ;
Demina, L. I. ;
Demin, S. V. ;
Shokurova, N. A. ;
Zhilov, V. I. ;
Tsivadze, A. Yu .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (03) :357-360
[20]   Separation of lithium isotopes by crown ether-room temperature ionic liquid-anisole friendly solvent system [J].
Liu, Bing ;
Jia, Yongzhong ;
Zhang, Zezheng ;
Sun, Huaxin ;
Yao, Ying ;
Jing, Yan ;
Qi, Mixiang ;
Zhang, Quanyou .
JOURNAL OF MOLECULAR LIQUIDS, 2021, 340
1234