Optimization and synthesis process of biodiesel production from coconut oil using central composite rotatable design of response surface methodology

被引:14
作者
Kannan, Rajesh [1 ]
Ramalingam, Sathiyamoorthi [2 ]
Sampath, Senthil [3 ]
Nedunchezhiyan, Mukilarasan [4 ]
Dillikannan, Damodharan [5 ]
Jayabal, Ravikumar [6 ]
机构
[1] RMK Coll Engn & Technol, Dept Mech Engn, Chennai, Tamil Nadu, India
[2] Chennai Inst Technol, Dept Mech Engn, Chennai, Tamil Nadu, India
[3] Panimalar Engn Coll, Dept Mech Engn, Chennai, Tamil Nadu, India
[4] Acad Maritime Educ & Training, Dept Mech Engn, Kanathur, Tamil Nadu, India
[5] Jeppiaar Engn Coll, Dept Mech Engn, Chennai, Tamil Nadu, India
[6] Saveetha Inst Med & Tech Sci, Saveetha Sch Engn, Dept Thermal Engn, Chennai, Tamil Nadu, India
关键词
Sustainable practices; waste to energy; coconut oil; biodiesel; free fatty acid; optimization; FATTY-ACID DISTILLATE; EMISSION CHARACTERISTICS; PERFORMANCE; TRANSESTERIFICATION; FUEL; ESTERIFICATION; NANOPARTICLES; METHANOL; WATER;
D O I
10.1177/09544089241230251
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
In the transportation and power production industries, the use of renewable and environmentally friendly fuels has grown in importance. Biodiesel derived from coconut oil contains over 90% saturated fatty acids. Biodiesel was made using alkaline transesterification since coconut oil has a free fatty acid content of less than 2.5%. Enzymatic or chemical transesterification are both possible. For the synthesis of coconut biodiesel, the optimal processing conditions are 60 degrees C for 1 h, a 6:1 ratio, 1% potassium hydroxide and a 95% yield. According to the experiment, 55 degrees C was the ideal reaction temperature for using coconut oil to produce biodiesel. Sixty minutes was the ideal amount of time to extract biodiesel from coconut oil. The methanol-to-oil molar ratio raised yield from 6:1 to 8:1, a 95% increase. Significant amounts of an alkaline catalyst, which allows soap to develop under the influence of fatty acids, are responsible for the high yield response; it is concluded that 1 wt% would be an appropriate catalyst concentration for the present investigation. The central composite rotatable design (CCRD) of the response surface methodology method is used to optimize several process parameters, including temperature, reaction duration, methanol-to-oil ratio and catalyst concentration. The CCRD optimization approach produced better results. The following are the final, optimized results: coconut oil methyl ester ratio: 96.69%, temperature: 55 degrees C; duration: 59.2 min; catalyst concentration: 0.7; molar ratio: 6.4.
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页数:11
相关论文
共 46 条
[1]   Development of a novel process for biodiesel production from palm fatty acid distillate (PFAD) [J].
Cho, Hyun Jun ;
Kim, Jin-Kuk ;
Hong, Seok Won ;
Yeo, Yeong-Koo .
FUEL PROCESSING TECHNOLOGY, 2012, 104 :271-280
[2]   A single step non-catalytic esterification of palm fatty acid distillate (PFAD) for biodiesel production [J].
Cho, Hyun Jun ;
Kim, Soo Hyun ;
Hong, Seok Won ;
Yeo, Yeong-Koo .
FUEL, 2012, 93 (01) :373-380
[3]   Optimization of Combustion Performance of Bioethanol (Water Hyacinth) Diesel Blends on Diesel Engine Using Response Surface Methodology [J].
Choudhary, Akhilesh Kumar ;
Chelladurai, H. ;
Kannan, C. .
ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING, 2015, 40 (12) :3675-3695
[4]  
De Poures MV., Journal of Cleaner Production, V371
[5]   Optimization of Injection System Parameter for CRDI Small Cylinder Diesel Engine by using Response Surface Method [J].
Dond D.K. ;
Gulhane N.P. .
Journal of The Institution of Engineers (India): Series C, 2021, 102 (04) :1007-1029
[6]   Optimization of microwave-assisted biodiesel production from waste catfish using response surface methodology [J].
Em Canh Pham ;
Tuong Vi Thi Le ;
Kim Chau Thi Le ;
Huong Ha Hong Ly ;
Bich Ngoc Thi Vo ;
Dat Van Nguyen ;
Tuyen Ngoc Truong .
ENERGY REPORTS, 2022, 8 :5739-5752
[7]   Conventional and in situ transesterification of sunflower seed oil for the production of biodiesel [J].
Georgogianni, K. G. ;
Kontominas, M. G. ;
Pomonis, P. J. ;
Avlonitis, D. ;
Gergis, V. .
FUEL PROCESSING TECHNOLOGY, 2008, 89 (05) :503-509
[8]   Converting waste cooking oil into biodiesel using phosphomolybdic acid/clinoptilolite as an innovative green catalyst via electrolysis procedure; optimization by response surface methodology (RSM) [J].
Helmi, Maryam ;
Tahvildari, Kambiz ;
Hemmati, Alireza ;
Azar, Parviz Aberoomand ;
Safekordi, Aliakbar .
FUEL PROCESSING TECHNOLOGY, 2022, 225
[9]   Strategic combination of waste plastic/tire pyrolysis oil with biodiesel for natural gas-enriched HCCI engine: Experimental analysis and machine learning model [J].
Hoang, Anh Tuan ;
Murugesan, Parthasarathy ;
Elumalai, P., V ;
Balasubramanian, Dhinesh ;
Parida, Satyajeet ;
Jayabal, Chandra Priya ;
Nachippan, Murugu ;
Kalam, M. A. ;
Truong, Thanh Hai ;
Cao, Dao Nam ;
Le, Van Vang .
ENERGY, 2023, 280
[10]  
Hoang T., 2017, Int J Renew Energy Dev, V6, P7