Nanoarchitectonics of Hollow Covalent Organic Frameworks: Synthesis and Applications

被引：76
作者：
Asakura, Yusuke [3 ]
Shuai, Qin [1 ]
Huang, Lijin [1 ]
Yang, Juan [2 ]
Yamauchi, Yusuke [3 ,4 ]
机构：
[1] China Univ Geosci, Fac Mat Sci & Chem, State Key Lab Biogeol & Environm Geol, Wuhan 430074, Peoples R China
[2] Wuhan Inst Technol, Sch Chem & Environm Engn, Key Lab Green Chem Proc,Minist Educ, Hubei Key Lab Novel Reactor & Green Chem Technol, Wuhan 430205, Hubei, Peoples R China
[3] Nagoya Univ, Grad Sch Engn, Dept Mat Proc Engn, Nagoya, Aichi 4648603, Japan
[4] Univ Queensland, Australian Inst Bioengn & Nanotechnol AIBN, Sch Chem Engn, Brisbane, Qld 4072, Australia
来源：
ACS NANO | 2023年 / 17卷 / 10期
基金：
中国国家自然科学基金;
关键词：
covalent organic frameworks; hollow structure; morphology modulation; dynamic covalent chemistry; advanced porous materials; derivatives; core-shell; nanoarchitecture engineering; ELECTROCHEMICAL ENERGY-STORAGE; IN-SITU ENCAPSULATION; PHOTOCATALYTIC PERFORMANCE; CARBON; COF; CONSTRUCTION; CRYSTALLINE; NANOSPHERES; FABRICATION; CONVERSION;
D O I：
10.1021/acsnano.3c01758
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hollow covalent organic frameworks (COFs) have gained significant attention because of their specific properties, including enhanced surface-to-volume ratio, large surface area, hierarchical structure, highly ordered nanostructures, and excellent chemical stability. These intrinsic characteristics endow hollow COFs with fascinating physicochemical properties and make them highly attractive for widespread applications, such as catalysis, energy storage, drug delivery, therapy, sensing, and environmental remediation. This review focuses on the recent developments in the synthesis of hollow COFs and their derivatives. In addition, their practical applications in various fields are summarized. Finally, challenges and future opportunities in terms of their synthetic methodologies and practical applications are discussed. Hollow COFs are expected to play an important role in the future of materials science.
引用
收藏
页码：8918 / 8934
页数：17
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