Mg-Doped CoCr2O4 Nanoparticles: Implications for Magnetic Memory and Magnetocaloric Effect

被引:11
|
作者
Manjunatha, Krishtappa [1 ]
Chiu, Hsin-Hao [1 ]
Ho, Ming-Kang [1 ]
Hsu, Tsu-En [1 ]
Yu, Shih-Lung [1 ]
Chin, Chu-En [1 ]
Cheng, Chia-Liang [1 ]
de Oliveira, Marisa Carvalho [2 ]
Longo, Elson [2 ]
Ribeiro, Renan A. P. [3 ]
Nagabhushana, Hanumanthappa [4 ]
Wu, Sheng Yun [1 ]
机构
[1] Natl Dong Hwa Univ, Dept Phys, Hualien 97401, Taiwan
[2] Fed Univ Sao Carlos UFSCar, Funct Mat Dev Ctr CDMF, BR-13565905 Sao Paulo, SP, Brazil
[3] Minas Gerais State Univ UEMG, Dept Nat & Earth Sci, BR-35501170 Divinopolis, MG, Brazil
[4] Tumkur Univ, Prof CNR Rao Ctr Adv Mat, Tumkur 572103, India
基金
巴西圣保罗研究基金会;
关键词
density functional theory; exchange bias effect; magnetic memory effect; magnetocaloric effect; ferrimagnetic; spin glass structures; SPIN; TEMPERATURE; TRANSITIONS; STATE;
D O I
10.1021/acsanm.3c01817
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Using the co-precipitate method, Mg-doped CoCr2O4 nanoparticles (NPs) with a particle size ranging from11to 22 nm were synthesized, and their structural, surface, vibrational,and magnetic properties were examined through experimental and theoreticalapproaches. The inherent magnetic inhomogeneity of the NPs was foundto be the cause of the observed exchange bias effect. The magneticmemory effect was studied below the spin glass-transition temperatureusing time- and temperature-dependent magnetization measurements,and the magnetocaloric effect was investigated across the Curie temperature.These NPs show promising potential for magnetic memory and magnetocaloriceffect fields.
引用
收藏
页码:12002 / 12015
页数:14
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