Metal-free reusable hollow-spherical triazine microporous organic polymer supported quinolines synthesis via hydrogen evolution

被引：6
作者：
Pathak, Debabrat [1 ]
Kalita, Bikash Kumar [1 ]
Sarmah, Ashish [1 ]
Sharma, Himanshu [1 ]
Bora, Bidisha [2 ]
Goswami, Tridib K. [2 ]
Sarma, Bipul [1 ]
机构：
[1] Tezpur Univ, Dept Chem Sci, Napam 784028, Assam, India
[2] Gauhati Univ, Dept Chem, Gauhati 781014, Assam, India
来源：
GREEN CHEMISTRY | 2023年 / 25卷 / 19期
关键词：
FRAMEWORKS; ALCOHOLS; CONSTRUCTION; REDUCTION; CATALYST;
D O I：
10.1039/d3gc02172f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the synthesis of medicinally and industrially valuable quinoline scaffolds, we report a one-pot greener synthetic route to do away with harsh reaction conditions, low productivity, and unstable substrates associated with the classical methods reported in the literature. Readily available alcohols undergo acceptorless dehydrogenative annulation in basic media over an engineered nitrogen-rich hollow-spherical microporous polymer (MOP-TA) devoid of any metal support. This affordable and sustainable route stands up to the test of scalability and green matrices, which are supported by various spectroscopic and microscopic techniques.
引用
收藏
页码：7642 / 7652
页数：11
相关论文
共 35 条
[1]   Metal-Free Chemoselective Reduction of Nitroarenes Catalyzed by Covalent Triazine Frameworks: The Role of Embedded Heteroatoms [J].
Abednatanzi, Sara ;
Derakhshandeh, Parviz Gohari ;
Dalapati, Sasanka ;
Veerapandian, Savita K. P. ;
Froissart, Anne-Claire ;
Epping, Jan Dirk ;
Morent, Rino ;
De Geyter, Nathalie ;
Van der Voort, Pascal .
ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (13) :15287-15297
[2]   Synthesis of Quinolines: A Green Perspective [J].
Batista, Vasco F. ;
Pinto, Diana C. G. A. ;
Silva, Artur M. S. .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (08) :4064-4078
[3]   Synthesis of Quinolines via a Metal-Catalyzed Dehydrogenative N- Heterocyclization [J].
Chelucci, Giorgio ;
Porcheddu, Andrea .
CHEMICAL RECORD, 2017, 17 (02) :200-216
[4]   Iron Single Atom Catalyzed Quinoline Synthesis [J].
Chen, Zhongxin ;
Song, Jingting ;
Peng, Xinwen ;
Xi, Shibo ;
Liu, Jia ;
Zhou, Wenhui ;
Li, Runlai ;
Ge, Rile ;
Liu, Cuibo ;
Xu, Haisen ;
Zhao, Xiaoxu ;
Li, Haohan ;
Zhou, Xin ;
Wang, Lu ;
Li, Xing ;
Zhong, Linxin ;
Rykov, Alexandre I. ;
Wang, Junhu ;
Koh, Ming Joo ;
Loh, Kian Ping .
ADVANCED MATERIALS, 2021, 33 (34)
[5]   Luminescent Covalent Organic Frameworks Containing a Homogeneous and Heterogeneous Distribution of Dehydrobenzoannulene Vertex Units [J].
Crowe, Jonathan W. ;
Baldwin, Luke A. ;
McGrier, Psaras L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (32) :10120-10123
[6]   Phosphine free Mn-complex catalysed dehydrogenative C-C and C-heteroatom bond formation: a sustainable approach to synthesize quinoxaline, pyrazine, benzothiazole and quinoline derivatives [J].
Das, Kalicharan ;
Mondal, Avijit ;
Srimani, Dipankar .
CHEMICAL COMMUNICATIONS, 2018, 54 (75) :10582-10585
[7]   Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction [J].
Ding, San-Yuan ;
Gao, Jia ;
Wang, Qiong ;
Zhang, Yuan ;
Song, Wei-Guo ;
Su, Cheng-Yong ;
Wang, Wei .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (49) :19816-19822
[8]   Covalent organic framework nanorods bearing single Cu sites for efficient photocatalysis [J].
Dong, Zhiyue ;
Zhang, Liang ;
Gong, Jiang ;
Zhao, Qiang .
CHEMICAL ENGINEERING JOURNAL, 2021, 403
[9]   Self-Templated Synthesis of Triphenylene-Based Uniform Hollow Spherical Two-Dimensional Covalent Organic Frameworks for Drug Delivery [J].
Du, Changsheng ;
Na, Wenjing ;
Shao, Mingchao ;
Shang, Shengcong ;
Liu, Yunqi ;
Chen, Jianyi .
CHEMISTRY OF MATERIALS, 2023, 35 (03) :1395-1403
[10]   Covalent Organic Framework-Covalent Organic Framework Bilayer Membranes for Highly Selective Gas Separation [J].
Fan, Hongwei ;
Mundstock, Alexander ;
Feldhoff, Armin ;
Knebel, Alexander ;
Gu, Jiahui ;
Meng, Hong ;
Caro, Juergen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (32) :10094-10098
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