Structural Change and Radical Generation of a Cadmium-Based Metal-Organic Framework Induced by an Electric Field

被引：3

作者：

Jin, Guo-Xia ^{[1
]}

Su, Zi-Lin ^{[1
]}

Han, Cong-Cong ^{[1
]}

Han, Li-Cong ^{[1
]}

Wang, Fu-Bo ^{[1
]}

Wu, Xiangwen ^{[1
]}

Zhao, Xianliang ^{[2
]}

Cai, Meichao ^{[3
]}

Wang, Haiying ^{[4
]}

Ma, Jian-Ping ^{[1
]}

机构：

[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Mol & Nano Probes, Minist Educ,Collaborat Innovat Ctr Functionalized, Jinan 250014, Peoples R China

[2] Zhejiang Univ Sci & Technol, Sch Biol & Chem Engn, Hangzhou 310023, Peoples R China

[3] Shandong Univ Tradit Chinese Med, Sch Pharm, Jinan 250355, Peoples R China

[4] Nanjing Xiaozhuang Univ, Sch Environm Sci, Nanjing 211171, Peoples R China

来源：

INORGANIC CHEMISTRY | 2023年 / 62卷 / 23期

基金：

中国国家自然科学基金;

关键词：

DESIGN; ADSORPTION; SEPARATION; COORDINATION; LIGANDS;

D O I：

10.1021/acs.inorgchem.3c01256

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hereinwe report the structural change and radical generation ofa cadmium-based metal-organic framework (Cd-MOF) induced byexternal electric fields. Under a weaker single electric field, differentcoordination modes of Cd-L lead to 3D -> 2D structuralchange. Under stronger superposed electric fields, Cd-MOF was excitedto produce a stable free radical. This study will provide a new avenuefor the controlled assembly of MOFs. External-electric-field-inducedstructural change and radicalgeneration of a cadmium-based metal-organic framework werestudied.

引用

页码：8784 / 8788

页数：5

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