Visible-light-mediated C(sp3)-H functionalization of alkyl arylacetates: an easy approach to S-benzyl dithiocarbamate acetates

被引:7
作者
Kumar, Mahesh [1 ]
Vishwakarma, Ramesh Kumar [1 ]
Preeti [1 ]
Singh, Krishna Nand [1 ]
机构
[1] Banaras Hindu Univ, Inst Sci, Dept Chem, Varanasi 221005, India
关键词
H BOND FUNCTIONALIZATION; ONE-POT SYNTHESIS; PHOTOREDOX CATALYSIS; EFFICIENT; STRAIGHTFORWARD; DISULFIDE; DESIGN; RUBBER;
D O I
10.1039/d2nj05285g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient visible light-promoted C(sp(3))-H functionalization of alkyl arylacetates has been developed using CS2 and amines by eosin Y/I-2 dual catalysis to achieve the formation of S-benzyl dithiocarbamate acetates.
引用
收藏
页码:2412 / 2416
页数:5
相关论文
共 49 条
[1]   Efficient, straightforward, catalyst-free synthesis of medicinally important S-alkyl/benzyl dithiocarbamates under green conditions [J].
Asadipour, Ali ;
Shams, Zeynab ;
Eskandari, Khalil ;
Moshafi, Mohammad-Hassan ;
Faghih-Mirzaei, Ehsan ;
Pourshojaei, Yaghoub .
RESEARCH ON CHEMICAL INTERMEDIATES, 2018, 44 (02) :1295-1304
[2]   A highly efficient synthesis of dithiocarbamates in green reaction media [J].
Azizi, Najmadin ;
Gholibeglo, Elham .
RSC ADVANCES, 2012, 2 (19) :7413-7416
[3]   Straightforward and highly efficient catalyst-free one-pot synthesis of dithiocarbamates under solvent-free conditions [J].
Azizi, Najmedin ;
Aryanasab, Fezzeh ;
Saidi, Mohammad R. .
ORGANIC LETTERS, 2006, 8 (23) :5275-5277
[4]   An efficient four-component synthesis of dithiocarbamate derivatives [J].
Azizi, Najmedin ;
Khajeh, Meysam ;
Hasani, Morteza ;
Dezfooli, Sahar .
TETRAHEDRON LETTERS, 2013, 54 (39) :5407-5410
[5]   One-pot copper nanoparticle-catalyzed synthesis of S-aryl- and S-vinyl dithiocarbamates in water: high diastereoselectivity achieved for vinyl dithiocarbamates [J].
Bhadra, Sukalyan ;
Saha, Amit ;
Ranu, Brindaban C. .
GREEN CHEMISTRY, 2008, 10 (11) :1224-1230
[6]   Determination of dithiocarbamate fungicide residues in food by a spectrophotometric method using a vertical disulfide reaction system [J].
Caldas, ED ;
Conceiçao, MH ;
Miranda, MCC ;
de Souza, LCKR ;
Lima, JF .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2001, 49 (10) :4521-4525
[7]   Synthesis and in vitro antitumor activity of 4(3H)-quinazolinone derivatives with dithiocarbamate side chains [J].
Cao, SL ;
Feng, YP ;
Jiang, YY ;
Liu, SY ;
Ding, GY ;
Li, RT .
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2005, 15 (07) :1915-1917
[8]   The medicinal chemist's toolbox for late stage functionalization of drug-like molecules [J].
Cernak, Tim ;
Dykstra, Kevin D. ;
Tyagarajan, Sriram ;
Vachal, Petr ;
Krska, Shane W. .
CHEMICAL SOCIETY REVIEWS, 2016, 45 (03) :546-576
[9]   Visible-Light Photoredox-Catalyzed Synthesis of trans-Oxiranes via Decarboxylative Stereospecific Epoxidation of trans-Cinnamic Acids by Aryldiazonium Salts [J].
Chand, Shiv ;
Sharma, Anup Kumar ;
Pandey, Anand Kumar ;
Singh, Krishna Nand .
ORGANIC LETTERS, 2022, 24 (35) :6423-6427
[10]   Visible-Light-Induced Photocatalytic Oxidative Decarboxylation of Cinnamic Acids to 1,2-Diketones [J].
Chand, Shiv ;
Pandey, Anand Kumar ;
Singh, Rahul ;
Singh, Krishna Nand .
JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (09) :6486-6493