Nickel-catalyzed reductive 1,1-diarylation of unactivated alkenes with aryl iodides

被引：4

作者：

Wang, Zhengwen ^{[1
]}

Jin, Zhou ^{[1
]}

Zhou, Bingwei ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2024年 / 11卷 / 05期

基金：

中国国家自然科学基金;

关键词：

REMOTE FUNCTIONALIZATION; HALIDES;

D O I：

10.1039/d3qo01812a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here we present a nickel-catalyzed reductive 1,1-diarylation reaction of unactivated alkenes with aryl iodides. 2,9-Dibutyl-1,10-phenanthroline was determined to be an optimal ligand for controlling the chemo-/regioselectivity towards 1,1-diarylated products. Aliphatic terminal alkenes bearing, respectively, ester, aryloxy and amino groups at the distal position were found to be competent for the 1,1-diarylation reaction, providing the terminal diarylated esters, ethers and amines in moderate to good yields.

引用

页码：1382 / 1387

页数：6

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