Heat Capacity and Thermodynamic Functions of Ho2O3•2HfO2 Solid Solution

被引:2
作者
Guskov, A. V. [1 ]
Gagarin, P. G. [1 ]
Guskov, V. N. [1 ]
Khoroshilov, A. V. [1 ]
Gavrichev, K. S. [1 ]
机构
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
基金
俄罗斯科学基金会;
关键词
holmium hafnium double oxide; calorimetry; Schottky anomaly; PHASE-EQUILIBRIA; ZIRCONIA; PYROCHLORES; COATINGS; OXIDES; HAFNIA; HO; ER; LN;
D O I
10.1134/S0036023623601903
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Isobaric heat capacity measurements in the range 2.4-1807 K have been performed by relaxation calorimetry, adiabatic calorimetry, and differential scanning calorimetry on a Ho2O3 center dot 2HfO(2) solid solution sample prepared and characterized by X-ray powder diffraction, electron microscopy, and chemical analysis, and thermodynamic functions have been calculated. The Schottky anomaly contribution has been determined in the range 2.4-300 K.
引用
收藏
页码:1592 / 1598
页数:7
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