CRYSTAL STRUCTURES OF TWO METAL-ORGANIC FRAMEWORKS BASED ON Zn(II) AND 2,5-DIIODOTEREPHTHALATE

被引：4

作者：

Zaguzin, A. S. ^{[1
,2
]}

Bondarenko, M. A. ^{[1
,2
]}

Sukhikh, T. S. ^{[1
]}

Fedin, V. P. ^{[1
]}

Adonin, S. A. ^{[1
,2
,3
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

[2] South Ural State Univ, Chelyabinsk, Russia

[3] Russian Acad Sci, Favorsky Inst Chem, Siberian Branch, Irkutsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2023年 / 64卷 / 11期

基金：

俄罗斯科学基金会;

关键词：

zinc; metal-organic frameworks; carboxylates; crystal structure; halogen bond; COORDINATION POLYMERS; BENZENE/CYCLOHEXANE SEPARATION; 5-IODO-ISOPHTHALIC ACID; LIGAND; MOF; SORPTION; ADSORPTION; CATALYST; SOLVENT; SERIES;

D O I：

10.1134/S0022476623110136

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three-dimensional coordination polymers Cat(2)[{Zn4O}(2)(H2O)(2)(2,5-I-bdc)(7)] (1) (2,5-I-bdc = 2,5-diiodoterephthalate, Cat is dimethylammonium) and [Zn-2(2,5-I-bdc)(2)dabco] (2) (dabco is 1,4-diazobicyclo [2.2.2]octane) are prepared. The structures of 1 and 2 are determined by single crystal X-ray diffraction. It is shown that the structure of 2 has a halogen bond between guest DMF molecules and the MOF iodine atom. The I center dot center dot center dot O distances are 2.93-3.03 angstrom.

引用

页码：2157 / 2166

页数：10

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