Synthesis and electrochemical evaluation of porous carbon derived from sanitary pad waste for high performance in symmetric supercapacitor application

被引:9
作者
Wesley, Ramachandran John [1 ]
Sowmya, Subramanian [1 ]
Durairaj, Arulappan [2 ]
Justinabraham, Romiyo [1 ]
Vijaikanth, Vijendran [1 ]
Obadiah, Asir [1 ]
Vasanthkumar, Samuel [1 ,3 ]
机构
[1] Karunya Inst Technol & Sci, Dept Appl Chem, Coimbatore 641114, India
[2] Bar Ilan Univ, Bar Ilan Inst Nanotechnol & Adv Mat, Dept Chem, IL-5290002 Ramat Gan, Israel
[3] Pelican Biotech & Chem Labs Pvt Ltd, Cherthala 688533, Kerala, India
关键词
Sanitary waste; Porous carbon; Aqueous electrolytes; Symmetric supercapacitor; ACTIVATED CARBON; OUTSTANDING SUPERCAPACITANCE; ULTRAHIGH CAPACITANCE; CHEMICAL ACTIVATION; ELECTRODE MATERIALS; COCONUT SHELL; LEAVES; COMPOSITES; CHALLENGES;
D O I
10.1016/j.est.2023.108662
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In recent years, the renewable energy storage system has attracted considerable attention from both industry and academia to address the ongoing global climate change. The waste derived porous materials gained attention as excellent electrode materials due to large specific area, good electrical conductivity to enhance ion transport and charge transfer. In this study, waste sanitary pad biomass has been successfully converted into carbon material through one-step simultaneous carbonization and activation by KOH. The as-prepared activated carbon at various temperatures was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray spectroscopy (XRD), scanning electron microscopy (SEM), Raman spectroscopy and Brunauer-Emmett-Teller (BET) tech-niques. The prepared biomass derived activated carbon (SWAC 800) electrode, with a large surface area of 396.1 m2g- 1 delivered high specific capacitance of 306 Fg-1 at 1 Ag-1 with excellent cyclic stability in a 6 M KOH aqueous electrolyte. The electrochemical performance of the SWAC 800 electrode in a symmetric supercapacitor was evaluated in 6 M KOH and 1 M Na2SO4 electrolytes. The neutral Na2SO4 electrolyte assist SWAC 800 symmetric supercapacitor device produce excellent energy density of 32.7 Wh.kg-1 in 1.6 V operating potential window. Overall the SWAC from renewable biowaste is prospective candidate for high performance electrode material for supercapacitor application.
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页数:12
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