Two Purely Inorganic Cationic Tellurite Materials Based on Group IB Metal Tetrafluoroborates with Similar Lamellar Cationic Layers: [Cu2F(Te2O5)](BF4) and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]•2HBF4

被引：0
|
作者：
Su, Tong [1 ,2 ,3 ]
Wei, Meiqiao [1 ,2 ]
Liu, Hanqing [3 ]
Fang, Yunshan [1 ,2 ]
Wu, Qiong [1 ,2 ]
Weng, Zhehui [1 ,2 ]
Ling, Jie [4 ]
Chen, Renjie [1 ,2 ]
Wang, Yulan [1 ,2 ]
Zhao, Xiusha [1 ,2 ]
Ju, Haidong [1 ,2 ]
机构：
[1] Kunming Univ, Sch Chem & Chem Engn, Yunnan Key Lab Met Organ Mol Mat & Device, Kunming 650214, Yunnan, Peoples R China
[2] Kunming Univ, Innovat Res Teams Sci & Technol Univ Yunnan Prov I, Kunming 650214, Yunnan, Peoples R China
[3] Polytech Ctr, Yunnan 678600, Peoples R China
[4] Univ Alabama Huntsville, Dept Chem, Huntsville, AL 35899 USA
来源：
INORGANIC CHEMISTRY | 2023年 / 62卷 / 25期
基金：
中国国家自然科学基金;
关键词：
CRYSTAL-STRUCTURES; ALKALI-METAL; COMPLEXES; COORDINATION; FRAMEWORK; ABSTRACTION; CERIUM(IV); MANGANESE; LIGANDS; SPECTRA;
D O I：
10.1021/acs.inorgchem.3c00856
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new purely inorganic cationic telluritenetworks, [Cu2F(Te2O5)](BF4)and [Ag18O2(Te4O9)(4)(Te3O8)(BF4)(2)]center dot 2HBF(4), have been hydrothermally synthesized under mild conditions,and both compounds exhibit similar lamellar cationic layers with intercalatedtetrafluoroborates ions. Magnetic analysis shows that [Cu2F(Te2O5)](BF4) exhibits a mainlyshort-range antiferromagnetic ordering within the 2D layer with aspin-singlet ground state. Further characterization of the physicalproperties includes powder XRD, IR and Raman spectroscopy, SEM-EDS,UV-vis-NIR diffuse reflectance, and TG analyses. Two new purely inorganic cationic tellurite networksof Group IBmetal-based tetrafluoroborates, namely, [Cu2F(Te2O5)](BF4), 1, and [Ag18O2(Te4O9)(4)(Te3O8)(BF4)(2)]center dot 2HBF(4), 2, have been hydrothermally synthesized under mildconditions. The prepared materials have been characterized by single-crystalX-ray diffraction, powder X-ray diffraction, IR and Raman spectroscopy,SEM-energy-dispersive spectroscopy, UV-vis-NIRdiffuse reflectance, magnetic study, and TG analyses. Single-crystaldiffraction studies show that both materials have similar cationicCu/Ag tellurite layers with tetrafluoroborates as interlamellar charge-balancinganions. Magnetic results indicate that [Cu2F(Te2O5)](BF4), 1, exhibits a mainlyshort-range antiferromagnetic ordering within the 2D layer, and furtherdetailed analysis of magnetic susceptibility analysis confirms a spin-singletground state with an energy gap of 85 K.
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页码：9882 / 9891
页数：10
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