Nickel complexes bearing N,N,N-tridentate quinolinyl anilido-imine ligands: Synthesis, characterization and catalysis in Suzuki-Miyaura cross-coupling reaction

被引：1
|
作者：
Zhou, Xiaoyu [1 ]
Xu, Hui [1 ]
Hao, Zhiqiang [1 ]
Han, Zhangang [1 ]
Lu, Guo-Liang [2 ]
Lin, Jin [1 ]
机构：
[1] Hebei Normal Univ, Coll Chem & Mat Sci, Natl Expt Chem Teaching Ctr, Hebei Key Lab Organ Funct Mol, Shijiazhuang 050024, Peoples R China
[2] Univ Auckland, Fac Med & Hlth Sci, Auckland Canc Soc Res Ctr, Private Bag 92019, Auckland 1142, New Zealand
来源：
POLYHEDRON | 2023年 / 246卷
关键词：
Anilido-Imine ligands; Nickel complexes; Suzuki-Miyaura cross-coupling; MOLECULAR-STRUCTURE; ARYL CHLORIDES; GENERAL-METHOD; PALLADIUM; POLYMERIZATION; BEHAVIOR; HALIDES;
D O I：
10.1016/j.poly.2023.116676
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four nickel complexes incorporating N,N,N-quinolinyl anilido-imine ligands based on ortho-C6H4F(CH = NAr) and 8-aminoquinoline, Ni[{2-[ArN = C(H)]C6H4}N(8-C9H6N)]Br (Ar = 2,6-iPr2C6H3 (1a), 2,4,6-(CH3)3C6H2 (1b), 4-BrC6H4 (1c)) and Ni[{2-[ArN = C(H)]C6H4}N(8-C9H6N)]2 (Ar = 4-ClC6H4 (1d)) were synthesized and structurally characterized by HR-MS, IR, NMR spectroscopy and X-ray crystallography. These nickel(II) complexes were used in Suzuki-Miyaura coupling and exhibited moderate to excellent catalytic activity with a low catalyst loading of 2.0 mol%.
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页数：11
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