Synthesis of internally carbon-sourced carbon nanofiber forming Ni-graphitic carbon nitride

被引：4

作者：

Bhaduri, Bhaskar ^{[1
]}

Omar, Rishabh Anand ^{[2
]}

Verma, Nishith ^{[3
,4
]}

机构：

[1] Indian Inst Technol Kharagpur, Dept Chem Engn, Kharagpur 721302, India

[2] Babasaheb Bhimrao Ambedkar Univ, Dept Environm Microbiol, Lucknow 226025, India

[3] Indian Inst Technol Kanpur, Ctr Environm Sci & Engn, Kanpur 208016, India

[4] Indian Inst Technol Kanpur, Dept Chem Engn, Kanpur 208016, India

来源：

CHEMICAL ENGINEERING SCIENCE | 2023年 / 274卷

关键词：

Carbon nanofibers; Graphitic carbon nitride; Chemical vapor deposition; Metal nanoparticles; Metal catalyst; ACTIVATED CARBON; NICKEL NANOPARTICLES; CU NANOPARTICLES; REMOVAL; GROWTH; TEMPERATURE; PERFORMANCE; ADSORPTION; ELECTRODES; OXIDATION;

D O I：

10.1016/j.ces.2023.118655

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The present study synthesizes carbon nanofibers (CNF) over a graphitic carbon nitride (g-C3N4) substrate without requiring an external carbon-source. In this novel route of the synthesis, g-C3N4 acts as the substrate as well as the internal source of carbon. Ni nanoparticles (NPs) dispersed in g-C3N4 catalyze the decomposition of triazine rings and N heterocycles in the material to form a web of CNF over g-C3N4. Tested for its catalytic activity towards the reduction of aqueous nitrobenzene (NB) using the hydrazine monohydrate reducing agent, Ni-CNF/g-C3N4 shows an approximately 95% conversion of NB. The high catalytic activity of the material is ascribed to the combined effects of g-C3N4, Ni NPs, and CNF. The present study has clearly established an efficient, easy, and inexpensive route for synthesizing CNF-based 3D nanostructures that are useful in many engineering applications including energy and environment.& COPY; 2023 Elsevier Ltd. All rights reserved.

引用

页数：11

共 72 条

[71] Carbon nitride derived nitrogen-doped carbon nanosheets for high-rate lithium-ion storage [J].