Desulfurization of coal using SnO2/TiO2 nanocomposite immobilized on glass beads under solar light irradiation

被引:0
作者
Ahmed, Zubair [2 ]
Bhatti, Ijaz A. [2 ]
Amjed, Nyla [3 ]
Mohsin, Muhammad [2 ]
Iqbal, Shahid [1 ]
Al Huwayz, Maryam [4 ]
Alwadai, Norah [4 ]
Nazir, Arif [3 ]
Iqbal, Munawar [1 ]
机构
[1] Univ Educ, Dept Chem, Div Sci & Technol, Lahore, Pakistan
[2] Univ Agr Faisalabad, Dept Chem, Faisalabad, Pakistan
[3] Univ Lahore, Dept Chem, Lahore, Pakistan
[4] Princess Nourah bint Abdulrahman Univ, Coll Sci, Dept Phys, POB 84428, Riyadh 11671, Saudi Arabia
来源
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2023年 / 237卷 / 08期
关键词
coal desulfurization; optimization; photocatalysis; SnO2; TiO2; nanocomposite; solar light irradiation; SNO2; NANOPARTICLES; TIO2; EQUILIBRIUM; DEGRADATION; ADSORPTION; KINETICS;
D O I
10.1515/zpch-2022-0084
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Coal is one of the important sources of energies and its combustion produce sulfur dioxide in the atmosphere, which needs desulphurization to avoids the pollution issue. Coal desulfurization was performed using SnO2/TiO2 nanocomposite under solar light irradiation. The SnO2/TiO2 was synthesized by co-precipitation method and deposited on glass beads. The prepared SnO2/TiO2 was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transfer infrared spectroscopy (FT-IR) techniques. The SnO2/TiO2 nanocomposite desulfurization efficiency was performed under solar light irradiation and process variables, i.e., irradiation time, H2O2 and pH were optimized for maximum desulfurization of coal. The SnO2/TiO2 nanocomposite showed promising efficiency and 60 % sulfur removal was achieved under optimum conditions. Based on efficiency, the SnO2/TiO2 nanocomposite has potential for the desulphurization of coal under solar light exposure, which will make the process highly economical feasible.
引用
收藏
页码:1125 / 1137
页数:13
相关论文
共 51 条
[21]   In situ diffuse reflectance infrared spectroscopy study of CO adsorption on SnO2 [J].
Emiroglu, S ;
Bârsan, N ;
Weimar, U ;
Hoffmann, V .
THIN SOLID FILMS, 2001, 391 (02) :176-185
[22]   Synthesis and characteristics of Fe3+-doped SnO2 nanoparticles via sol-gel-calcination or sol-gel-hydrothermal route [J].
Fang, L. M. ;
Zu, X. T. ;
Li, Z. J. ;
Zhu, S. ;
Liu, C. M. ;
Zhou, W. L. ;
Wang, L. M. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 454 (1-2) :261-267
[23]   Synthesis and characterization of magnetically separable La1-xBixCr1-yFeyO3 and photocatalytic activity evaluation under visible light [J].
Ghafoor, Aamir ;
Bibi, Ismat ;
Ata, Sadia ;
Majid, Farzana ;
Kamal, Shagufta ;
Rehman, Fariha ;
Iqbal, Shahid ;
Aamir, Muhammad ;
Slimani, Yassine ;
Iqbal, Munawar ;
Mailk, Abdul .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2021, 235 (11) :1413-1431
[24]  
Hamilton-Amachree A, 2020, DOI [10.5281/zenodo.3516565, 10.5281/zenodo.3516565, DOI 10.5281/ZENODO.3516565]
[25]   Excess conductivity and AC susceptibility studies of Y-123 superconductor added with TiO2 nano-wires [J].
Hannachi, E. ;
Slimani, Y. ;
Ekicibil, A. ;
Manikandan, A. ;
Ben Azzouz, F. .
MATERIALS CHEMISTRY AND PHYSICS, 2019, 235
[26]   Higher intra-granular and inter-granular performances of YBCO superconductor with TiO2 nano-sized particles addition [J].
Hannachi, E. ;
Slimani, Y. ;
Ben Azzouz, F. ;
Ekicibil, A. .
CERAMICS INTERNATIONAL, 2018, 44 (15) :18836-18843
[27]   Kinetic and thermodynamic studies for evaluation of adsorption capacity of fungal dead biomass for direct dye [J].
Hassan, Asma ;
Bhatti, Haq Nawaz ;
Iqbal, Munawar ;
Nazir, Arif .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2021, 235 (08) :1077-1097
[28]  
Iqbal M., 2020, Z PHYS CHEM, V235, P1209
[29]   Gamma radiation/H2O2 treatment of a nonylphenol ethoxylates: Degradation, cytotoxicity, and mutagenicity evaluation [J].
Iqbal, Munawar ;
Bhatti, Ijaz Ahmad .
JOURNAL OF HAZARDOUS MATERIALS, 2015, 299 :351-360
[30]  
Jafarinejad S., 2017, Chem. Int, V3, P342, DOI [10.31221/osf.io/fu27y, DOI 10.31221/OSF.IO/FU27Y, DOI 10.5281/ZENODO.1473343]