Decoration of ruthenium nanoparticles on nitrogen and phosphorus-doped carbon as a robust catalyst for the reduction of nitroarenes

被引：4

作者：

Dabiri, Minoo ^{[1
]}

Salmasi, Aram Mnachekanian ^{[1
]}

Salarinejad, Neda ^{[1
]}

Movahed, Siyavash Kazemi ^{[2
]}

机构：

[1] Shahid Beheshti Univ, Fac Chem & Petr Sci, Dept Organ Chem & Oil, Tehran 1983969411, Iran

[2] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2023年 / 1287卷

关键词：

HIGHLY EFFICIENT; CHEMOSELECTIVE HYDROGENATION; SUPERCAPACITORS; COMPOSITE; OXIDATION; CORE;

D O I：

10.1016/j.molstruc.2023.135609

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ruthenium nanoparticles (NPs) were decorated on nitrogen and phosphorus-doped carbon derived from phosphorus zeolitic imidazolate frameworks (P-ZIFs) via a facile in-situ doping-carbonization method. As-synthesized nanostructures were used as a heterogeneous catalyst for the chemoselective reduction of aromatic nitro compounds to the corresponding amines under ambient conditions. In contrast, P-ZIF-8 and P-ZIF-67-derived catalysts showed poor activity, while P-BMZIF-derived catalyst demonstrated high catalytic activity. Also, it was found that phosphorus on carbon layers improved catalytic efficiency when added to the carbon layers

引用

页数：8

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