Facile synthesis of the SnTe/SnSe binary nanocomposite via a hydrothermal route for flexible solid-state supercapacitors

被引:102
作者
Abdullah, Muhammad [1 ]
John, Peter [1 ]
Fawy, Khaled Fahmi [2 ]
Manzoor, Sumaira [3 ]
Butt, Kashif Younas [4 ]
Abid, Abdul Ghafoor [3 ]
Messali, Mouslim [5 ]
Najam-Ul-Haq, Muhammad [3 ]
Ashiq, Muhammad Naeem [3 ]
机构
[1] Govt Coll Univ, Dept Chem, Lahore, Pakistan
[2] King Khalid Univ, Fac Sci, Dept Chem, POB 9004, Abha 61413, Saudi Arabia
[3] Bahauddin Zakariya Univ, Inst Chem Sci, Multan 60800, Pakistan
[4] Univ Lahore, Dept Chem, Lahore, Pakistan
[5] Imam Mohammad Ibn Saud Islamic Univ, Coll Sci, Dept Chem, POB 90950, Riyadh 11623, Saudi Arabia
关键词
ELECTRODE MATERIAL; NI FOAM; PERFORMANCE; GROWTH;
D O I
10.1039/d3ra01028g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Environmental degradation and energy shortage are the two biggest problems facing the world right now. Because of the limited supply of non-renewable sources, the production of environment-friendly energy and its storage has gained significant importance. Pseudocapacitors have lately caught the interest of energy specialists due to their greater energy/power density and prolonged cycle life. In this work, binding-free SnTe/SnSe (STSS) electrodes deposited onto Ni foam (NF) as the conductive substrate have been developed by a facile hydrothermal route for supercapacitor applications. Several analytical tools were utilized to study the morphological, structural and textural characteristics. The electrochemical results obtained from a three-electrode system suggest that the STSS electrode material exhibits great specific capacitance (C-s) of 1276 F g(-1), specific energy (E-d) of 46.45 W h kg(-1) and specific power (P-d) of 256 W kg(-1) @ 1 A g(-1). The results of C-dl indicate that the STSS (31.28 mF) has a larger C-dl value than those of SnTe (23.22 mF) and SnSe (26.35 mF). The analysis of electrochemical stability indicates that the STSS displays structural stability over 5000 cycles with a maximum capacitance retention of 96%. The Nyquist plot profile displayed a smaller R-ct value for STSS (0.89 ?) than SnSe (1.13 ?) and SnTe (1.97 ?). The symmetric behavior of STSS was determined in 2.0 M potassium hydroxide. The results reveal that this material has a specific capacitance of 537.72 F g(-1) and specific energy of 78.32 W h kg(-1). These findings suggest that the STSS electrode might serve as a potential candidate for supercapacitors and other energy-saving equipment.
引用
收藏
页码:12009 / 12022
页数:14
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