Cubic-phase NaYF4:Pr3+, Yb3+down-conversion phosphors for optical temperature sensing

被引:4
作者
Pudovkin, M. S. [1 ,3 ]
Kuznetsov, S. V. [1 ,2 ]
Konuyshkin, V. A. [2 ]
Nakladov, A. N. [2 ]
Voronov, V. V. [2 ]
机构
[1] Kazan Fed Univ, Inst Phys, 18 Kremlyovskaya Str, Kazan 420008, Russia
[2] Russian Acad Sci, Prokhorov Gen Phys Inst, 38 Vavilov Str, Moscow 119991, Russia
[3] Kazan Fed Univ, Dept Quantum Elect & Radiospect, 18 Kremljovskaya Str, Kazan 420008, Russia
基金
俄罗斯科学基金会;
关键词
Cubic-phase NaYF4; Pr3+; Yb3+; Down-conversion; Luminescent thermometry; Optical temperature sensors; UP-CONVERSION; EARTH; DOWNCONVERSION; LUMINESCENCE; EMISSION; YB3+;
D O I
10.1016/j.ssc.2023.115235
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The cubic phase NaYF4:Pr3+, Yb3+ single crystals were grown in the resistive furnace by the BridgmanStockbarger technique with following milling in an agate mortar. The luminescence intensity ratio (LIR) between 3P1 - 3H5 and 3P0 - 3H5 emissions of Pr3+ was taken a temperature-dependent parameter. The calculated absolute (Sa) temperature sensitivity was 0.0075 at 320 K. The LIR between 3P0 - 1G4 (Pr3+) and 2F5/2 - 2F7/2 (Yb3+) emissions is also temperature-dependent due to phonon-assisted nature of energy transfer between 1G4 of Pr3+ and 2F5/2 of Yb3+. Sr and Sa demonstrated the highest values in the 100-220 K temperature range (Sa (max) = 0.0047 K-1 at 150 K).NaYF4:Pr3+, Yb3+ samples are useful in optical temperature sensing in the broad temperature range from 100 up to 320 K.
引用
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页数:7
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