Fe-doped CdS with sulfonated g-C3N4 in a heterojunction designed for improved biomedical and photocatalytic potentials

被引:6
作者
Iftikhar, Afsah [1 ]
Javed, Mohsin [2 ]
Mansoor, Sana [2 ]
Mahmood, Sajid [3 ,4 ]
Iqbal, Shahid [3 ,9 ]
Aslam, Muhammad [1 ,9 ]
Jazaa, Yosef [5 ]
Alshalwi, Matar [6 ]
Lateef, Mehreen [7 ]
Habib, Farzana [8 ]
Habibullah, Khansa [1 ]
Bahadur, Ali [9 ,10 ]
机构
[1] Univ Educ, Dept Chem, Div Sci & Technol, Lahore, Pakistan
[2] Univ Management & Technol, Sch Sci, Dept Chem, Lahore 54770, Pakistan
[3] Univ Nottingham Ningbo China, Nottingham Ningbo China Beacons Excellence Res & I, Ningbo 315100, Peoples R China
[4] Gulf Univ Sci & Technol, Funct Mat Grp, Mishref 32093, Kuwait
[5] King Khalid Univ, Fac Engn, POB 9004, Abha 61413, Saudi Arabia
[6] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11541, Saudi Arabia
[7] Bahria Univ Med & Dent Coll, Multidisciplinary Res Lab, Karachi, Pakistan
[8] PCSIR Labs Complex, Pakistan Inst Technol Minerals & Adv Engn Mat, Lahore, Pakistan
[9] Wenzhou Kean Univ, Coll Sci Math & Technol, Dept Chem, Wenzhou 325060, Zhejiang Provin, Peoples R China
[10] Kean Univ, Dorothy & George Hennings Coll Sci Math & Technol, 1000 Morris Ave, Union, NJ 07083 USA
关键词
Fe-doped CdS NPs; Co-precipitation method; Photocatalytic activity; Antibacterial activity; METAL-ORGANIC FRAMEWORKS; GRAPHITIC CARBON NITRIDE; CO2; REDUCTION; VISIBLE-LIGHT; WATER; NANOPARTICLES; OXIDE; DEGRADATION; OXIDATION; BACTERIA;
D O I
10.1016/j.inoche.2024.112205
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the present study, nano -catalysts such as (purified CdS, S-g-C3N4, 9 %Fe@CdS NPs, and 9 %Fe@CdS with 50 % S-g-C3N4 nanocomposites) are created by the co -precipitation method. Thiourea was thermally decomposed to make Graphitic carbon nitride doped with sulphur. A distinct heterostructure emerged between Fe/CdS and Sulfur doped g-C3N4 would result in a greater number of heterojunctions and more active areas to increase photocatalytic breakdown. The characterization techniques that were used include scanning electron microscope, EDX, XRD, Fourier transform Infrared, and UV-visible spectroscopy. The outcomes showed that iron infusion changed CdS's structural makeup. Using MB as a reference dye, the absorbance for photocatalytic oxidation behavior was measured using a UV-Vis spectrophotometer. Among the doped NPs, 9 percent Fe -doped CdS with 50 % S -doped g-C3N4 removes 94 % Methylene Blue (MB) dye. According to the results, the MB dye color entirely vanished after three hours. Additionally, doped CdS and composite were studied for their antibacterial characteristics. The bactericidal activity of 9 percent Fe -doped CdS with 50 percent SCN was exceptional. The standard (BHA) at the same concentration shows an inhibition value, IC50 value = 44.2 +/- 0.24 mu M while for 9 % Fe -doped CdS nanocomposite with SCN, the DPPH scavenging activity was inhibited potently (IC50 value = 59.8.5 0.78 mu M). SCN incorporation resulted in increased surface area of the composite and decreased e-/ h + pair recombination.
引用
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页数:10
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