The L-proline modified Zr-based MOF (Basu-proline) catalyst for the one-pot synthesis of dihydropyrano[3,2-c]chromenes

被引：13
作者：
Benrashid, Amin [1 ]
Habibi, Davood [1 ]
Beiranvand, Masoumeh [1 ]
Gilan, Maryam Mahmoudiani [1 ]
机构：
[1] Bu Ali Sina Univ, Dept Organ Chem, Fac Chem, Hamadan, Hamadan, Iran
来源：
SCIENTIFIC REPORTS | 2023年 / 13卷 / 01期
关键词：
ENANTIOSELECTIVE SYNTHESIS; ACID; NANOCATALYST; ADSORPTION; EFFICIENT; GREEN;
D O I：
10.1038/s41598-023-44774-4
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
A novel, reusable, and efficient L-proline-modified Zr-based metal-organic framework (Basu-proline) was designed, synthesized, and characterized by Fourier Transform-Infrared spectroscopy (FT-IR), Energy-Dispersive X-ray spectroscopy (EDX), elemental mapping, Field Emission Scanning Electron Microscopy (FE-SEM), X-ray Diffraction analysis (XRD), Thermo-Gravimetric-Differential Thermal Analysis (TGA-DTA), and N-2 adsorption-desorption isotherms. Then, its catalytic performance was assessed in the synthesis of dihydropyrano[3,2-c]chromenes via the one-pot, three-component tandem condensation reaction of 4-hydroxycoumarin, aromatic aldehydes and malononitrile. The Basu-proline catalyst exhibited a better efficiency than some reported protocols regarding higher yields, lower reaction times, and simple separation.
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页数：16
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