Light-activation of SF5Cl for the atom transfer radical addition onto alkenes and alkynes

被引：7
|
作者：
Berger, Marie-Rose Ouellet-Du [1 ]
Boucher, Maxim [1 ]
Paquin, Jean-Francois [1 ]
机构：
[1] Univ Laval, Dept Chim, PROTEO, CGCC, Quebec City, PQ G1V 0A6, Canada
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2023年 / 268卷
基金：
加拿大自然科学与工程研究理事会;
关键词：
Pentafluorosulfanyl substituent; Chloropentafluorosulfanylation; Radical addition; Light activation; Photochemistry; PENTAFLUOROSULFANYL GROUP; SUBSTITUENTS; CONVENIENT; CHLORIDE;
D O I：
10.1016/j.jfluchem.2023.110131
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A reagent-free activation method for the addition of SF5Cl on unsaturated compounds was developed using a blacklight compact fluorescent lamp irradiation. A total of 19 examples of alkenes and alkynes were performed, with yields ranging from 25% to 99%. Overall, this method represents an oxygen-free alternative to the most common SF5Cl addition reaction conditions.
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收藏
页数：7
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