Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology

被引：2
|
作者：
Zhang, Fengyan [1 ,2 ]
Dong, Yonglu [6 ]
Lin, Shudong [1 ,2 ,3 ,4 ,5 ]
Gui, Xuefeng [1 ,3 ,4 ,5 ]
Hu, Jiwen [1 ,2 ,3 ,4 ,5 ,6 ]
机构：
[1] Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Guangdong Prov Key Lab Organ Polymer Mat Elect, Guangzhou 510650, Peoples R China
[4] CAS Engn Lab Special Fine Chem, Guangzhou 510650, Peoples R China
[5] CASH GCC Shaoguan Res Inst Adv Mat, Nanxiong 512400, Peoples R China
[6] Shaoguan NanXiong Hiteac Ind Dev Zone, Management Comm, Nanxiong 512400, Peoples R China
来源：
POLISH JOURNAL OF CHEMICAL TECHNOLOGY | 2023年 / 25卷 / 02期
基金：
中国国家自然科学基金;
关键词：
soybean oil; response surface methodology; epoxidation; oxirane value; BOX-BEHNKEN DESIGN; FORMED IN-SITU; OXIRANE CLEAVAGE; EPOXIDATION; KINETICS; ACID; RING;
D O I：
10.2478/pjct-2023-0013
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The epoxidation process of soybean oil (SBO) and peracid produced by 50 wt% hydrogen peroxide (H2O2) and formic acid (FA) was studied with sulfuric acid (H2SO4) as a catalyst. Three reaction parameters, including reaction temperature, FA-to-SBO ratio, and H2O2-to-SBO ratio, were investigated, along with the combined effect on oxirane value (OV). Based on response surface methodology (RSM), the Box-Behnken design (BBD) was used to optimize the process parameters. According to the results, the calculated OV (7.34%) and the experimental OV (7.31%) were signifi cantly in agreement. The product was confi rmed as epoxidized soybean oil (ESO) by IR and NMR characterization methods. These results demonstrated the reliability of RSM to optimize the SBO reaction to produce ESO with high oxygen content.
引用
收藏
页码：21 / 29
页数：9
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