Synthesis of Zeolitic Imidazolate Framework-8 Using Glycerol Carbonate

被引：9

作者：

Itatani, Masaki ^{[1
]}

Nemet, Norbert ^{[1
,2
]}

Valletti, Nadia ^{[3
]}

Schuszter, Gabor ^{[4
]}

Prete, Prisco ^{[5
]}

Lo Nostro, Pierandrea ^{[6
]}

Cucciniello, Raffaele ^{[5
,7
]}

Rossi, Federico ^{[3
]}

Lagzi, Istvan ^{[1
,8
]}

机构：

[1] Budapest Univ Technol & Econ, Inst Phys, Dept Phys, H-1111 Budapest, Hungary

[2] Budapest Univ Technol & Econ, Dept Organ Chem & Technol, H-1111 Budapest, Hungary

[3] Univ Siena, Dept Phys Sci Earth & Environm, I-53100 Siena, Italy

[4] Univ Szeged, Dept Phys Chem & Mat Sci, H-6720 Szeged, Hungary

[5] Univ Salerno, Dept Chem & Biol, I-84084 Salerno, Italy

[6] Univ Firenze, Dept Chem Ugo Schiff, I-50019 Florence, Italy

[7] Acad Nazl Lincei, Ctr Interdisciplinare Linceo Giovani, I-00165 Rome, Italy

[8] Budapest Univ Technol & Econ, ELKH BME Condensed Matter Res Grp, H-1111 Budapest, Hungary

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2023年 / 11卷 / 35期

关键词：

metal-organic framework (MOF); zeolitic imidazolateframework (ZIF); recycle; solvents; porousmaterials; ROOM-TEMPERATURE SYNTHESIS; WATER-BASED SYNTHESIS; ZIF-8; NANOCRYSTALS; NANOPARTICLES; ADSORPTION; REACTIVITY; MORPHOLOGY; STABILITY; SOLVENT; SIZE;

D O I：

10.1021/acssuschemeng.3c02876

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Glycerolcarbonate can be used as a green solvent for synthesizingzeolitic imidazole framework-8, which can be also recycled for severalcycles. In this study, we show that glycerol carbonate (GlyC),a bio-basedderivative of glycerol, can be used as a suitable green solvent forthe synthesis of metal-organic frameworks (MOFs). In particular,a zinc-based zeolitic imidazolate framework-8 (ZIF-8) was synthesizedby exploring several different experimental conditions (in terms oftemperature, reaction time, and reactants' concentrations)to find that the yield of the reaction and the quality of the products,measured in terms of crystallinity, surface area, and porosity, werein line with those obtained in the most commonly (non-green) usedsolvents. GlyC was also found to be reusable for several cycles, maintainingthe same original quality as a solvent for the synthesis. Finally,some indicators for the assessment of the greenness of a process (E-factorand PMI) revealed a milder environmental impact of GlyC with respectto other solvents.

引用

页码：13043 / 13049

页数：7

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