Transition metal-free and regioselective alkenyl C-S cross-coupling reaction of alkenylsulfonium salts

被引：9

作者：

Wang, Qiang ^{[1
]}

Wu, Shuaijie ^{[1
]}

Wang, Yi-Dong ^{[1
]}

Sun, Jing ^{[1
]}

Han, Ying ^{[1
]}

Yan, Chao-Guo ^{[1
]}

Wang, Lei ^{[1
]}

机构：

[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 12期

基金：

中国国家自然科学基金;

关键词：

PALLADIUM-CATALYZED ARYLATION; ADDITION-CYCLIZATION REACTIONS; VINYL SULFONIUM SALTS; ARYL SULFENATE ANIONS; ENANTIOSELECTIVE ARYLATION; ASYMMETRIC-SYNTHESIS; SULFOXIDES; DERIVATIVES; ALKYLATION; EFFICIENT;

D O I：

10.1039/d3qo00507k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Herein, we report a novel and highly efficient strategy for the construction of alkenyl sulfoxides via transition metal-free C-S cross-coupling of sulfenate anions with alkenylsulfonium salts. This procedure features the capture of in situ generated sulfenate anions from beta-sulfinyl esters under mild conditions, which provides an efficient strategy for the synthesis of diverse alkenyl sulfoxides in moderate to good yields.

引用

页码：2907 / 2912

页数：6

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