Modification of activated carbon from agricultural waste lotus leaf and its adsorption mechanism of beryllium

被引:13
作者
Zhao, Xu [1 ]
Su, Yucheng [2 ]
Wang, Hongqiang [2 ]
Lei, Zhiwu [2 ,3 ]
Hu, Eming [2 ]
Hu, Fang [2 ]
Wang, Qingliang [2 ]
Xu, Lechang [4 ]
Fan, Shiyao [2 ]
Liu, Xinwei [2 ]
Hao, Xuanzhang [2 ]
机构
[1] Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Hunan, Peoples R China
[2] Univ South China, Sch Resource Environm & Safety Engn, Hengyang 421001, Hunan, Peoples R China
[3] East China Univ Technol, State Key Lab Nucl Resources & Environm, Nanchang 330013, Jiangxi, Peoples R China
[4] CNNC, Beijing Res Inst Chem Engn & Met, Tongzhou Dist, Beijing 101149, Peoples R China
关键词
Langmuir Freundlich Beryllium Activated Carbon; AQUEOUS-SOLUTIONS; REMOVAL; ISOTHERMS; ADSORBENT; KINETICS; SORPTION; IONS; COAL;
D O I
10.1007/s11814-022-1251-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
With the wide application of beryllium globally, industrial wastewater has rapidly increased. Previously, adsorption was effective in treating this issue. However, most adsorbents have a poor removal rate, primarily in the low adsorption capacity. To remove Be from industrial wastewater and overcome the disadvantages of low adsorption capacity and poor removal rate of existing adsorbents, typical agricultural waste lotus leaf was used to prepare Al-activated carbon (Al-AC) by the impregnation-calcination modification of Al(NO3)(3). The theoretical maximum adsorption capacity of Al-AC was 32.86 mg/g. Langmuir, Freundlich, and Temkin models were used to thermodynamically analyze Al-AC, and adsorption thermodynamics demonstrated that the adsorption reaction of Al-AC was endothermic. Through characterization analysis, the specific surface area of the modified AC increased from 4.3573 to 155.87 m(2)/g. This study provides a new approach to preparing and modifying AC and a new method for removing Be from industrial wastewater.
引用
收藏
页码:255 / 266
页数:12
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