Naphthalene-Based Polymers as Catalytic Supports for Suzuki Cross-Coupling

被引:1
|
作者
Bakhvalova, Elena S. [1 ]
Bykov, Alexey V. [2 ]
Markova, Mariia E. [2 ]
Lugovoy, Yury V. [2 ]
Sidorov, Alexander I. [2 ]
Molchanov, Vladimir P. [2 ]
Sulman, Mikhail G. [2 ]
Kiwi-Minsker, Lioubov [1 ,3 ]
Nikoshvili, Linda Z. [2 ]
机构
[1] Tver State Univ, Reg Technol Ctr, Zhelyabova Str 33, Tver 170100, Russia
[2] Tver State Tech Univ, Dept Biotechnol Chem & Standardizat, ANikitina Str 22, Tver 170026, Russia
[3] Ecole Polytech Fed Lausanne, IS FSB EPFL, CH-1015 Lausanne, Switzerland
来源
MOLECULES | 2023年 / 28卷 / 13期
基金
俄罗斯科学基金会;
关键词
naphthalene; Friedel-Crafts crosslinking; sulfonation; nitration; palladium; Suzuki cross-coupling; HYPERCROSSLINKED POLYSTYRENE; SELECTIVE HYDROGENATION; MICROPOROUS POLYMERS; LINKED POLYMER; NANOPARTICLES; PERFORMANCE; SULFONATION; PALLADIUM; ACID;
D O I
10.3390/molecules28134938
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
In this work, for the first time, naphthalene (NA)-based polymers were synthesized by one-stage Friedel-Crafts crosslinking. The influence of NA functionalization by -OH, -SO3H, and -NO2 groups on the polymers' porosity and distribution of the catalytically active phase (Pd) was studied. Synthesized catalytic systems containing 1 wt.% of Pd either in the form of Pd(II) species or Pd(0) nanoparticles supported on NA-based polymers were tested in a model reaction of Suzuki cross-coupling between 4-bromoanisole and phenylboronic acid under mild reaction conditions (60 & DEG;C, ethanol-water mixture as a solvent). These novel catalysts demonstrated high efficiency with more than 95% of 4-bromoanisole conversion and high selectivity (>97%) for the target 4-methoxybiphenyl.
引用
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页数:22
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