In this work, for the first time, naphthalene (NA)-based polymers were synthesized by one-stage Friedel-Crafts crosslinking. The influence of NA functionalization by -OH, -SO3H, and -NO2 groups on the polymers' porosity and distribution of the catalytically active phase (Pd) was studied. Synthesized catalytic systems containing 1 wt.% of Pd either in the form of Pd(II) species or Pd(0) nanoparticles supported on NA-based polymers were tested in a model reaction of Suzuki cross-coupling between 4-bromoanisole and phenylboronic acid under mild reaction conditions (60 & DEG;C, ethanol-water mixture as a solvent). These novel catalysts demonstrated high efficiency with more than 95% of 4-bromoanisole conversion and high selectivity (>97%) for the target 4-methoxybiphenyl.
机构:A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences Russia,Organic and Medicinal Chemistry, Dr. Reddy’s Institute of Life Sciences
N. V. Kuchkina
M. Rajadurai
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机构:A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences Russia,Organic and Medicinal Chemistry, Dr. Reddy’s Institute of Life Sciences
M. Rajadurai
M. Pal
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机构:A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences Russia,Organic and Medicinal Chemistry, Dr. Reddy’s Institute of Life Sciences
M. Pal
S. Basaveni
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机构:A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences Russia,Organic and Medicinal Chemistry, Dr. Reddy’s Institute of Life Sciences
S. Basaveni
S. A. Sorokina
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机构:A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences Russia,Organic and Medicinal Chemistry, Dr. Reddy’s Institute of Life Sciences
S. A. Sorokina
I. Yu. Krasnova
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机构:A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences Russia,Organic and Medicinal Chemistry, Dr. Reddy’s Institute of Life Sciences
I. Yu. Krasnova
E. S. Serkova
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机构:A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences Russia,Organic and Medicinal Chemistry, Dr. Reddy’s Institute of Life Sciences
E. S. Serkova
Z. B. Shifrina
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机构:A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences Russia,Organic and Medicinal Chemistry, Dr. Reddy’s Institute of Life Sciences
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Seoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South KoreaSeoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South Korea
Hong, Kootak
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Sajjadi, Mohaddeseh
Suh, Jun Min
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Seoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South KoreaSeoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South Korea
Suh, Jun Min
Zhang, Kaiqiang
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Seoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South KoreaSeoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South Korea
Zhang, Kaiqiang
Nasrollahzadeh, Mahmoud
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Univ Qom, Fac Sci, Dept Chem, Qom 3716146611, IranSeoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South Korea
Nasrollahzadeh, Mahmoud
Jang, Ho Won
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Seoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South KoreaSeoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South Korea
Jang, Ho Won
Varma, Rajender S.
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Palacky Univ, Fac Sci, Reg Ctr Adv Technol & Mat, Dept Phys Chem, Olomouc 78371, Czech RepublicSeoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South Korea
Varma, Rajender S.
Shokouhimehr, Mohammadreza
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Seoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South KoreaSeoul Natl Univ, Dept Mat Sci & Engn Res, Inst Adv Mat, Seoul 08826, South Korea