Crystal structures and Hirshfeld surface analyses of tetrakis(4,5-dihydrofuran-2-yl)silane and tetrakis(4,5-dihydrofuran-2-yl)germane

被引：0
作者：
Ressel, Arnold [1 ]
Krupp, Anna [1 ]
Strohmann, Carsten [1 ]
机构：
[1] Tech Univ Dortmund, Fak Chem & Chem Biol Anorgan Chem, Otto Hahn Str 6, D-44227 Dortmund, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; dihydrofuranyl groups (DHF); Hirshfeld surface analysis; dihydrofurylsilan; dihydrofurylgermane; GE-C BONDS; SI-C; CLEAVAGE;
D O I：
10.1107/S2056989023003158
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compounds Si(C4H5O)(4) (1) and Ge(C4H5O)(4) (2) are dihydrofuryl compounds of silicon and germanium and are useful building blocks for the functionalization of these elements. Both structures crystallize in space group P2(1)/n in the monoclinic crystal system with two molecules in the asymmetric unit: the Si and Ge atoms adopt slightly distorted tetrahedral geometries, while the C4H5O moieties exhibit shallow envelope conformations. Through a Hirshfeld surface analysis of the structures, interactions within the crystal packing could be elucidated: compound 1 features a polymeric chain in the (101) plane via C-H center dot center dot center dot O hydrogen bonds whereas in 2 C-H center dot center dot center dot O hydrogen bonds create a polymeric chain in the (010) plane.
引用
收藏
页码：458 / +
页数：22
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