Crystal structures and Hirshfeld surface analyses of tetrakis(4,5-dihydrofuran-2-yl)silane and tetrakis(4,5-dihydrofuran-2-yl)germane

被引：0
|
作者：
Ressel, Arnold [1 ]
Krupp, Anna [1 ]
Strohmann, Carsten [1 ]
机构：
[1] Tech Univ Dortmund, Fak Chem & Chem Biol Anorgan Chem, Otto Hahn Str 6, D-44227 Dortmund, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; dihydrofuranyl groups (DHF); Hirshfeld surface analysis; dihydrofurylsilan; dihydrofurylgermane; GE-C BONDS; SI-C; CLEAVAGE;
D O I：
10.1107/S2056989023003158
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compounds Si(C4H5O)(4) (1) and Ge(C4H5O)(4) (2) are dihydrofuryl compounds of silicon and germanium and are useful building blocks for the functionalization of these elements. Both structures crystallize in space group P2(1)/n in the monoclinic crystal system with two molecules in the asymmetric unit: the Si and Ge atoms adopt slightly distorted tetrahedral geometries, while the C4H5O moieties exhibit shallow envelope conformations. Through a Hirshfeld surface analysis of the structures, interactions within the crystal packing could be elucidated: compound 1 features a polymeric chain in the (101) plane via C-H center dot center dot center dot O hydrogen bonds whereas in 2 C-H center dot center dot center dot O hydrogen bonds create a polymeric chain in the (010) plane.
引用
收藏
页码：458 / +
页数：22
相关论文
共 50 条
  • [21] Crystal structures of (5RS)-(Z)-4-[5-(furan-2-yl)-3 phenyl-4,5-dihydro-1H-pyrazol-1-yl]-4-oxobut-2enoic acid and (5RS)-(Z)-4-[5-(furan-2-yl)-3-(thiophen-2-yl)-4,5-dihydro-1H-pyrazol-1-yl]-4-oxobut-2-enoic acid
    Borisova, Kseniya K.
    Toze, Flavien A. A.
    Yagafarov, Nniyaz Z.
    Zubkov, Fedor I.
    Dorovatovskii, Pavel V.
    Zuhavichus, Yan V.
    Khrustalev, Victor N.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1557 - +
  • [22] Crystal structure of 4-[1-(2-hydroxypropyl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid
    Jasinski, Jerry P.
    Mohamed, Shaaban K.
    Akkurt, Mehmet
    Abdelhamid, Antar A.
    Albayati, Mustafa R.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O77 - U304
  • [23] Crystal structure and Hirshfeld surface analysis of 4-bromo-2-[3-methyl-5-(2,4,6-trimethylbenzyl)-oxazondin-2-yl]phenol
    Khalilov, Ali N.
    Khrustalev, Victor N.
    Fortalnova, Elena A.
    Akkurt, Mehmet
    Yildirim, Sema Ozturk
    Bhattarai, Ajaya
    Mamedov, Ibrahim G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 695 - +
  • [24] Structural characterization and Hirshfeld surface analysis of the pyrazoline 1-(3-(4-iodophenyl)-5-(3-methylthiophen-2-yl)-4,5-dihydro-1H-pyrazol-1-yl)ethan-1-one
    Delgado, Gerzon E.
    Liew, Suk-Ming
    Jamalis, Joazaizulfazli
    Cisterna, Jonathan
    Cardenas, Alejandro
    Brito, Ivan
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1210
  • [25] Crystal structures, phase transition, and Hirshfeld surface analyses of the bromide and chloride congeners of aqua[2,4,6-tris(pyridin-4-yl)-1,3,5-triazine]zinc(II) halide
    Dailey, Maegan
    Jackson, Eric W.
    Ramadhar, Timothy R.
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2024, 80 : 545 - +
  • [26] Crystal structure and Hirshfeld surface analysis of N-(5-iodo-4-phenylthiazol-2-yl)acetamide
    Herrera-Espana, Angel D.
    Aguilera-Gonzalez, Jesus
    Mena-Rejon, Gonzalo J.
    Hernandez-Ortega, Simon
    Caceres-Castillo, David
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 717 - +
  • [27] The crystal structures, Hirshfeld surface analyses and energy frameworks of 8-{1-[3-(cyclopent-l-en-1-yl)benzyl)piperidin-4-yl}-2-methoxyquinoline and 8-{4-[3-(cyclopent-1-en-1-yl)benzyl]piperazin-1-yl}-2-methoxyquinoline
    Ullah, Nisar
    Stoeckli-Evans, Helen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 372 - +
  • [28] The crystal structures and Hirshfeld surface analyses of four 3,5-diacetyl-2-methyl-2,3-dihydro-1,3,4-thiadiazol-2-yl derivatives
    NizamMohideen, M.
    Abuthahir, S. Syed
    Viswanathan, V.
    Velmurugan, D.
    Ananth, M. Karthik
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1436 - +
  • [29] Crystal structure and Hirshfeld surface analysis of 2-[(2-oxo-2H-chromen-4-yl)oxy]acetic acid dimethyl sulfoxide monosolvate
    Abuthahir, S. Syed
    NizamMohideen, M.
    Viswanathan, V.
    Govindhan, M.
    Subramanian, K.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1123 - +
  • [30] Crystal structure and Hirshfeld surface analysis of dimethyl 2-oxo-4-(pyridin-2-yl)-6-(thiophen-2-yl)cyclohex-3-ene-1,3-dicarboxylate
    Naghiyev, Farid N.
    Khrustalev, Victor N.
    Akkurt, Mehmet
    Huseynov, Elnur Z.
    Bhattarai, Ajaya
    Khalilov, Ali N.
    Mamedov, Ibrahim G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 654 - +
12345