Crystal structures and Hirshfeld surface analyses of tetrakis(4,5-dihydrofuran-2-yl)silane and tetrakis(4,5-dihydrofuran-2-yl)germane

被引：0
|
作者：
Ressel, Arnold [1 ]
Krupp, Anna [1 ]
Strohmann, Carsten [1 ]
机构：
[1] Tech Univ Dortmund, Fak Chem & Chem Biol Anorgan Chem, Otto Hahn Str 6, D-44227 Dortmund, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; dihydrofuranyl groups (DHF); Hirshfeld surface analysis; dihydrofurylsilan; dihydrofurylgermane; GE-C BONDS; SI-C; CLEAVAGE;
D O I：
10.1107/S2056989023003158
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compounds Si(C4H5O)(4) (1) and Ge(C4H5O)(4) (2) are dihydrofuryl compounds of silicon and germanium and are useful building blocks for the functionalization of these elements. Both structures crystallize in space group P2(1)/n in the monoclinic crystal system with two molecules in the asymmetric unit: the Si and Ge atoms adopt slightly distorted tetrahedral geometries, while the C4H5O moieties exhibit shallow envelope conformations. Through a Hirshfeld surface analysis of the structures, interactions within the crystal packing could be elucidated: compound 1 features a polymeric chain in the (101) plane via C-H center dot center dot center dot O hydrogen bonds whereas in 2 C-H center dot center dot center dot O hydrogen bonds create a polymeric chain in the (010) plane.
引用
收藏
页码：458 / +
页数：22
相关论文
共 50 条
  • [1] Crystal structures and Hirshfeld surface analyses of bis(4,5-dihydrofuran-2-yl)dimethylsilane and (4,5-dihydrofuran-2-yl)(methyl)diphenylsilane
    Schmidt, Annika
    Krupp, Anna
    Barth, Eva Rebecca
    Strohmann, Carsten
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 23 - +
  • [2] Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris(4,5-dihydrofuran-2-yl)methylsilane and tris(4,5-dihydrofuran-2-yl)phenylsilane
    Krupp, Anna
    Barth, Eva Rebecca
    Seymen, Rana
    Strohmann, Carsten
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 1514 - +
  • [3] Crystal Structure of Tetrakis(2,2′-bithiophene-5-yl)silane
    Stoica, Elena Bianca
    Branger, Catherine
    Iordache, Tanta Verona
    Sarbu, Andrei
    Iovu, Horia
    Vitrik, Oleg B.
    Dyshlyuk, Anton, V
    Brisset, Hugues
    MATERIALE PLASTICE, 2018, 55 (03) : 255 - 257
  • [4] Bis[2-(4,5-diohenyl-1H-imidazol-2-yl)-4-nitro-phenolato]copper(II) dihydrate: crystal structure and Hirshfeld surface analysis
    Chettri, Sailesh
    Brahman, Dhiraj
    Sinha, Biswajit
    Jotani, Mukesh M.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1664 - +
  • [5] Crystal structures and Hirshfeld surface analyses of 2-[(4,6-diaminopyrimidin-2-yl)sulfanyl]-N-(pyridin-2-yl)acetamide and 2-[(4,6-diaminopyrimidin-2-yl)-sulfanyl]-N-(pyrazin-2-yl)acetamide
    Choudhury, Manisha
    Viswanathan, Vijayan
    Timiri, Ajay Kumar
    Sinha, Karij Nayan
    Jayaprakash, Venkatesan
    Velmurugan, Devadasan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 718 - +
  • [6] Synthesis, crystal structure and Hirshfeld surface analysis of (1H-benzimidazol-2-yl)(morpholin-4-yl)methanethione
    Mutalliev, Lukmonjon Z.
    Abdullaev, Sirojiddin
    Pirnazarova, Nasiba
    Obidova, Ibodat
    Turgunov, Kambarali
    Yakubov, Ubaydullo
    Ashurov, Jamshid M.
    Elmuradov, Burkhan Zh
    Mamadrakhimov, Azimjon A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 999 - +
  • [7] Synthesis, crystal structure and Hirshfeld surface analysis of 4-[3-(4-hydroxyohenyl)-4,5-dihydro-1H-pyrazol-5-yl]-2-methoxypnenol monohydrate
    Linh Duong Khanh
    My Hanh Trinh Thi
    Thuy Quynh Bui Thi
    Trung Vu Quoc
    Vuong Nguyen Thien
    Luc Van Meervelt
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1590 - +
  • [8] 2,2,6,6-Tetrakis(biphenyl-2-yl)-4,4,8,8-tetramethylcyclotetrasiloxane
    Couzijn, Erik P. A.
    Lutz, Martin
    Spek, Anthony L.
    Lammertsma, Koop
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2182 - U2270
  • [9] Crystal structures and Hirshfeld surface analyses of 4-benzyl-6-phenyl-4,5-dinvdropyriaazin-3(2H)-one and methyl 2-[5-(2,6-dichlorobenzyl)-6-oxo-3-phenyl-1,4,5,6-tetrahydropyridazin-1-yl]acetate
    Dadou, Said
    Kansiz, Sevgi
    Daoui, Said
    El Kalai, Fouad
    Baydere, Cemile
    Saddik, Rafik
    Karrouchi, Khalid
    Dege, Necmi
    Benchat, Noureddine
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1679 - +
  • [10] Crystal structure, Hirshfeld surface analysis and DFT studies of 6-[(E)-2-(thiophen-2-yl)etnenyl]-4,5-dihydropyridazin-3(2H)-one
    Daoui, Said
    Cinar, Emine Berrin
    El Kalai, Fouad
    Saddik, Rafik
    Dege, Necmi
    Karrouchi, Khalid
    Benchat, Noureddine
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1880 - +
12345