Multi-stimuli-responsive supramolecular polymer via orthogonal pillararene-based host-guest and π- π interactions

被引：5
作者：
Li, Yong-Fu [1 ]
Wang, Xin [1 ]
Wang, Chun-Yu [1 ,2 ]
Wang, Yan [1 ]
Yang, Ying-Wei [1 ]
机构：
[1] Jilin Univ, Coll Chem, Int Joint Res Lab Nanomicro Architecture Chem, 2699 Qianjin St, Changchun 130012, Peoples R China
[2] Jilin Univ, Inst Theoret Chem, Coll Chem, State Key Lab Supramol Struct & Mat,Lab Theoret &, Changchun 130012, Peoples R China
来源：
TETRAHEDRON | 2023年 / 149卷
基金：
中国国家自然科学基金;
关键词：
Supramolecular polymer; Pillararene; Stimuli-responsive; Orthogonal assembly; Smart materials; MOLECULAR RECOGNITION; SYSTEM; CONSTRUCTION; ASSEMBLIES; EMISSION; NETWORK; PHOTO; DIMER; POLARITY; REMOVAL;
D O I：
10.1016/j.tet.2023.133718
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We designed and prepared a supramolecular assembly-induced emission enhancement supramolecular polymer (PyP5 subset of S2NH2) via rational combination host-guest and pi- pi stacking interactions between pyrenefunctionalized pillar[5]arene host (PyP5) and the bis(dialkylammonium salt)-based BB type guest (S2NH2). With the increasing concentration of S2NH2 and PyP5, the structures of PyP5 subset of S2NH2 transformed from linear to cross-linked networks. Moreover, PyP5 subset of S2NH2 can be sensitive to multiple stimuli, including temperature, redox, UV-light, pH, solvent polarity, organometallic compound, and competitive guest. This work paves the way to develop fluorescent supramolecular polymers with multi-stimuli-responsive properties via facilely supramolecular approaches.
引用
收藏
页数：8
相关论文
共 75 条
[1]   Pillar[5]arene-Based 3D Hybrid Supramolecular Polymer for Green Catalysis in Water [J].
Cai, Yan ;
Yan, Xin ;
Wang, Siyuan ;
Zhu, Zhiwen ;
Cen, Moupan ;
Ou, Changjin ;
Zhao, Qin ;
Yan, Qian ;
Wang, Jin ;
Yao, Yong .
INORGANIC CHEMISTRY, 2021, 60 (05) :2883-2887
[2]   Pillar[5]arene-Based Resilient Supramolecular Gel with Dual-Stimuli Responses and Self-Healing Properties [J].
Chen, Jin-Fa ;
Chen, Pangkuan .
ACS APPLIED POLYMER MATERIALS, 2019, 1 (08) :2224-2229
[3]   Pillar[5]arene-based multifunctional supramolecular hydrogel: multistimuli responsiveness, self-healing, fluorescence sensing, and conductivity [J].
Chen, Jin-Fa ;
Lin, Qi ;
Yao, Hong ;
Zhang, You-Ming ;
Wei, Tai-Bao .
MATERIALS CHEMISTRY FRONTIERS, 2018, 2 (05) :999-1003
[4]   Self-assembled supramolecular artificial light-harvesting nanosystems: construction, modulation, and applications [J].
Chen, Xu-Man ;
Chen, Xiao ;
Hou, Xiao-Fang ;
Zhang, Shu ;
Chen, Dongzhong ;
Li, Quan .
NANOSCALE ADVANCES, 2023, 5 (07) :1830-1852
[5]   Pillararene-Based Aggregation-Induced-Emission-Active Supramolecular System for Simultaneous Detection and Removal of Mercury(II) in Water [J].
Cheng, Hong-Bo ;
Li, Ziyan ;
Huang, Yao-Dong ;
Liu, Lei ;
Wu, Hai-Chen .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (13) :11889-11894
[6]   Supramolecular Assembly-Induced Emission Enhancement for Efficient Mercury(II) Detection and Removal [J].
Dai, Dihua ;
Li, Zheng ;
Yang, Jie ;
Wang, Chunyu ;
Wu, Jia-Rui ;
Wang, Yan ;
Zhang, Dongmei ;
Yang, Ying-Wei .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (11) :4756-4763
[7]   Photo-responsive linear and cross-linked supramolecular polymers based on host-guest interactions [J].
Dong, Shengyi ;
Gao, Lingyan ;
Li, Jinying ;
Xu, Donghua ;
Zhou, Qizhong .
POLYMER CHEMISTRY, 2013, 4 (14) :3968-3973
[8]   Preparation of a Diblock Supramolecular Copolymer via Self-Sorting Organization [J].
Dong, Shengyi ;
Zheng, Bo ;
Zhang, Mingming ;
Yan, Xuzhou ;
Ding, Xia ;
Yu, Yihua ;
Huang, Feihe .
MACROMOLECULES, 2012, 45 (22) :9070-9075
[9]   A Dual-Responsive Supramolecular Polymer Gel Formed by Crown Ether Based Molecular Recognition [J].
Dong, Shengyi ;
Luo, Yan ;
Yan, Xuzhou ;
Zheng, Bo ;
Ding, Xia ;
Yu, Yihua ;
Ma, Zhi ;
Zhao, Qiaoling ;
Huang, Feihe .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (08) :1905-1909
[10]   Cell polarity proteins and cancer [J].
Ellenbroek, Saskia I. J. ;
Iden, Sandra ;
Collard, John G. .
SEMINARS IN CANCER BIOLOGY, 2012, 22 (03) :208-215
12345678