A route to carbon-sp3 bridging spiro-molecules: synthetic methods and optoelectronic applications

被引：8

作者：

Chen, Yong ^{[1
,2
,3
,4
]}

Xu, Jianbin ^{[2
,3
,4
]}

Gao, Peng ^{[2
,3
,4
]}

机构：

[1] Jiangxi Univ Sci & Technol, Fac Mat Met & Chem, Ganzhou 341000, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China

[3] Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Peoples R China

[4] Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Lab Adv Funct Mat, Xiamen 361021, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2024年 / 11卷 / 02期

基金：

中国国家自然科学基金;

关键词：

HOLE-TRANSPORT MATERIAL; PEROVSKITE SOLAR-CELLS; ACTIVATED DELAYED FLUORESCENCE; CIS-STILBENE/FLUORENE HYBRIDS; HIGHLY EFFICIENT; LOW-COST; LUMINESCENT MATERIALS; BUILDING-BLOCKS; CHARGE-TRANSFER; DOPANT-FREE;

D O I：

10.1039/d3qo01735d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Molecules with spiro-linked pi-conjugated structures have attracted considerable attention in the realm of organic functional materials due to their advantageous structural features. In this review, we comprehensively summarize the synthetic methodologies utilized to create spiro molecules encompassing cyclopentane, cyclohexane, and cycloheptane frameworks. Furthermore, we investigate the diverse applications of these spiro molecules in the field of photovoltaics. Additionally, we elaborate on the synthesis of spiro molecules incorporating an embedded carbonyl group and probe their multifaceted applications across various domains.

引用

页码：508 / 539

页数：32

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