Electronic agglomeration effect of Co-O sites in ultrafine cobalt oxide coupled CNT accelerating ORR kinetic activity for hybrid sodium-air battery

被引:5
作者
Kang, Yao [1 ,2 ,3 ]
Li, Jianding [4 ]
机构
[1] Univ Sanya, Sch New Energy & Intelligent Networked Automobile, Sanya 572022, Peoples R China
[2] Zhejiang Geely Holding Grp Co Ltd, Hangzhou 310051, Peoples R China
[3] Zhejiang Intelligent Transportat Technol Innovat C, Ningbo 315000, Peoples R China
[4] Huzhou Univ, Sch Sci, Huzhou Key Lab Mat Energy Convers & Storage, Huzhou 313000, Peoples R China
关键词
Florine anions; Electronic agglomeration effect; Oxygen reduction reaction; Hybrid sodium-air battery; OXYGEN REDUCTION REACTION; NANOPARTICLES; CATALYST; DESIGN;
D O I
10.1016/j.electacta.2024.143854
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Hybrid sodium-air batteries (HSABs) offer a possible solution for large-scale energy storage due to high theoretical energy density and abundant sodium resource. However, ORR suffers from sluggish kinetics with multielectron transfer step, resulting in high overpotential. Herein, we demonstrated electronic agglomeration effect on CoO/CNT to controllably activate catalytic active species to boost ORR by atomic surface engineering. By virtues of superior electron transfer ability and optimal adsorption energy of reactive species, activities of F- surface-decorated electrode could be greatly improved. DFT revealed that F- induced electronic agglomeration on Co -O sites, resulting in high electron density of Co and intense combination with OH* in the first step. Surprisingly, the F-CoO/CNT showed favorable ORR activity and enabled advanced HSAB with low overpotential gap of 0.14 V. This work provides a new view about atomic and electronic structure engineering for activating active species, which will pave a new way for designing electrode materials.
引用
收藏
页数:9
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