Progress and Advances in Porous Silica-based Scaffolds for Enhanced Solid-state Hydrogen Storage: A Systematic Literature Review

Hydrogen plays a crucial role in the future energy landscape owing to its high energy density. However, finding an ideal storage material is the key challenge to the success of the hydrogen economy. Various solid-state hydrogen storage materials, such as metal hydrides, have been developed to realize safe, effective, and compact hydrogen storage. However, low kinetics and thermodynamic stability lead to a high working temperature and a low hydrogen sorption rate of the metal hydrides. Using scaffolds made from porous materials like silica to confine the metal hydrides is necessary for better and improved hydrogen storage. Therefore, this article reviews porous silica-based scaffolds as an ideal material for improved hydrogen storage. The outcome showed that confining the metal hydrides using scaffolds based on porous silica significantly increases their storage capacities. It was also found that the structural modifications of the silica-based scaffold into a hollow structure further improved the storage capacity and increased the affinity and confinement ability of the metal hydrides, which prevents the agglomeration of metal particles during the adsorption/desorption process. Hence, the structural modifications of the silica material into a fibrous and hollow material are recommended to be crucial for further enhancing the metal hydride storage capacity. This review explores recent developments in nanomaterial-based solid-state hydrogen storage, focusing on the potential of silica-based scaffolds for enhancing hydrogen storage materials. Specifically, porous silica-based scaffolds emerge as promising candidates to improve hydrogen storage, with a key emphasis on nanoconfinement of metal hydrides. The enhancement of storage capacity is deemed essential, and structural modifications, such as adopting a hollow-fibrous structure, are recommended. This not only improves storage capacity but also enhances the affinity and confinement ability of the metal hydrides.image