A CHARGE-ASSISTED HYDROGEN-BONDED ORGANIC FRAMEWORK FOR SELECTIVE SEPARATION OF p-XYLENE

被引:0
作者
Shi, Chundiao [1 ]
Li, Ziling [1 ]
Xiang, Shengchang [1 ]
Liu, Chulong [1 ]
Zheng, Ximing [2 ]
机构
[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Prov Key Lab Polymer Mat, Fuzhou 350117, Peoples R China
[2] Wuyi Univ, Wuyishan 354300, Peoples R China
来源
QUIMICA NOVA | 2024年 / 47卷 / 05期
关键词
hydrogen-bonded organic framework; p-xylene separation; selectivity; ISOMERS;
D O I
10.21577/0100-4042.20230134
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A charge-assisted hydrogen-bonded organic framework (HOF) FJU-201 is constructed by N,N'-bis(5-isophthalic acid)naphthalimide divalent anion (H2L2-), p-xylene and dimethylammonium. FJU-201 can only crystallize in solutions containing p-xylene, and cannot crystallize in both o-xylene and m-xylene. FJU-201 can also crystallize in xylene mixtures with the content of p-xylene is not less than 50%, which can be used for separating and purifying p-xylene, and it has good recyclability.
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页数:5
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