Recognizing the potential of K-salts, apart from KOH, for generating porous carbons using chemical activation

被引:142
作者
Singh, Gurwinder [1 ]
Ruban, Ajanya Maria [1 ]
Geng, Xun [1 ]
Vinu, Ajayan [1 ]
机构
[1] Univ Newcastle, Coll Engn Sci & Environm CESE, Global Innovat Ctr Adv Nanomat GICAN, Univ Dr, Callaghan, NSW 2308, Australia
关键词
Chemical activation; Potassium salts; Porous carbons; High surface area; Mechanism of activation; HIGH-SURFACE-AREA; GRAPHITIC BIOMASS CARBON; HIGH-NITROGEN-CONTENT; CO2; ADSORPTION; K2CO3; ACTIVATION; POTASSIUM-CITRATE; FACILE SYNTHESIS; METHANE STORAGE; SYNTHESIZE NITROGEN; ELECTRODE MATERIALS;
D O I
10.1016/j.cej.2022.139045
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Due to their high porosity, chemically activated porous carbons find extensive use in various applications including gas capture, energy storage, and environmental remediation. Such porous carbons are predominantly produced using KOH as a chemical activating agent, which is highly corrosive, toxic, and harmful to the envi-ronment. As an alternative, several other potassium-based salts including K2CO3, KHCO3, K3C6H5O7, KC2H3O2, K2C2O4, K2FeO4, and K2SO4 can also produce high porosity in the porous carbons via chemical activation with negligible detrimental effects on the environment. This review, which is the first of its kind, discusses the use-fulness of various K-salts, other than KOH, in producing porous carbons with competitive results in terms of various physico-chemical features and their impact on various application fields. This review also discusses the methodology and mechanistic aspects of various K-salts for chemical activation. Up-to-date literature is reviewed for the above-mentioned purposes that would provide the readers with useful information on the evolution of various K-salts, other than KOH, for their usefulness and future potential in chemical activation to produce highly efficient porous carbons for various applications.
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页数:23
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共 200 条
[1]   Porous carbons from sustainable sources and mild activation for targeted high-performance CO2 capture and storage [J].
Aljumialy, Abdulsalam M. ;
Mokaya, Robert .
MATERIALS ADVANCES, 2020, 1 (09) :3267-3280
[2]   Predictable and targeted activation of biomass to carbons with high surface area density and enhanced methane storage capacity [J].
Altwala, Afnan ;
Mokaya, Robert .
ENERGY & ENVIRONMENTAL SCIENCE, 2020, 13 (09) :2967-2978
[3]   Activated carbon monoliths with hierarchical pore structure from tar pitch and coal powder for the adsorption of CO2, CH4 and N2 [J].
Arami-Niya, Arash ;
Rufford, Thomas E. ;
Zhu, Zhonghua .
CARBON, 2016, 103 :115-124
[4]   Preparation of salacca peel-based porous carbons by K2CO3 activation method as cathode materials for LiS battery [J].
Arie, Arenst Andreas ;
Kristianto, Hans ;
Cengiz, Elif Ceylan ;
Demir-Cakan, Rezan .
CARBON LETTERS, 2020, 30 (02) :207-213
[5]   Optimized waste tea activated carbon for adsorption of Methylene Blue and Acid Blue 29 dyes using response surface methodology [J].
Auta, M. ;
Hameed, B. H. .
CHEMICAL ENGINEERING JOURNAL, 2011, 175 :233-243
[6]   Generalized Mechanochemical Synthesis of Biomass-Derived Sustainable Carbons for High Performance CO2 Storage [J].
Balahmar, Norah ;
Mitchell, Andrew C. ;
Mokaya, Robert .
ADVANCED ENERGY MATERIALS, 2015, 5 (22)
[7]   Adsorption of organic and inorganic pollutants on activated bio-carbons prepared by chemical activation of residues of supercritical extraction of raw plants [J].
Bazan-Wozniak, Aleksandra ;
Pietrzak, Robert .
CHEMICAL ENGINEERING JOURNAL, 2020, 393
[8]   Hydrogen Storage in Porous Materials: Status, Milestones, and Challenges [J].
Berenguer-Murcia, Angel ;
Pablo Marco-Lozar, Juan ;
Cazorla-Amoros, Diego .
CHEMICAL RECORD, 2018, 18 (7-8) :900-912
[9]   Influence of surface properties on electro-chemical supercapacitors utilizing Callerya atropurpurea pod derived porous nanocarbons: Structure property relationship between porous structures to energy storage devices [J].
Bhat, Vinay S. ;
Supriya, S. ;
Jayeoye, Titilope John ;
Rujiralai, Thitima ;
Sirimahachai, Uraiwan ;
Chong, Kwok Feng ;
Hegde, Gurumurthy .
NANO SELECT, 2020, 1 (02) :226-243
[10]   Nitrogen and Oxygen Co-doped Hierarchical Porous Carbon Derived from Pine Mushroom Biomass for High-Performance Supercapacitor [J].
Bian, Zhentao ;
Zhao, Guangzhen ;
Chao, Long ;
Liu, Chengcheng ;
Zhao, Mingkun ;
Wang, Hongyan ;
Xie, Yong ;
Zhu, Guang ;
Chen, Chong .
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2020, 15 (08) :8296-8310