Volumetric and viscometric properties of L-glutamic acid in aqueous L-arabinose and D-xylose solutions between the temperature range of (293.15-313.15) K at atmospheric pressure

被引:7
作者
Pradhan, Rupesh Kumar [1 ]
Sahoo, Lokanath [2 ]
Singh, Sulochana [1 ]
机构
[1] Siksha O Anusandhan Deemed Univ, Dept Chem, ITER, Bhubaneswar, Odisha, India
[2] GangadharMeher Univ, Sch Chem, Sambalpur 768004, Odisha, India
关键词
L-glutamic acid; Carbohydrates; Apparent molar volume; Transfer properties; Thermodynamic study; APPARENT MOLAR VOLUMES; PLUS WATER SOLUTIONS; SOLVENT INTERACTIONS; THERMODYNAMIC PROPERTIES; AMINO-ACIDS; INTERACTION PARAMETERS; HEAT-CAPACITIES; ASPARTIC-ACID; VISCOSITY; CHLORIDE;
D O I
10.1016/j.jct.2023.107193
中图分类号
O414.1 [热力学];
学科分类号
摘要
To investigate the molecular interaction among nonessential amino acids and carbohydrates in this article we report the density and viscosityresultsof L-glutamic acid in aqueous solutions of L-arabinose and D-xylose over an integral composition regime (2.00 wt%, 2.50 wt% and 3.01 wt%)at atmospheric pressure (101 kPa) and at temperature range of 293.15, 298.15, 303.15, 308.15 and 313.15 K. The experimental density values were used to evaluate apparent molal volume (V null ), partial apparent molal volume (V0 null ), limiting apparent molal expansibility (E0 null ) and Hepler's constant ( partial differential 2V0 null / partial differential T2)P. The values of viscosity were used to calculate viscosity co-efficients AF (Falkenhagen coefficients) and BJ (Jones-Dole coefficients), temperature derivative of BJ, Gibbs free energy of activation (Delta mu 0,# 1 , Delta mu 0,# 2 ) and thermodynamic parameters like Delta H0#2 and Delta S0#2 . A thorough interpretation of the results obtained from the thermodynamic as well as physicochemical properties reveal a potent ion-solvent interactions in the aqueous solution of Glu andGlubehaves as a structure maker in the presence of L-arabinose/D-xylose.
引用
收藏
页数:16
相关论文
共 69 条
[11]  
Beri A, 2020, FOOD FUNCT, V11, P1006, DOI [10.1039/c9fo00872a, 10.1039/C9FO00872A]
[12]   Molecular interactions of two biologically active molecules (L-serine and L-valine) in aqueous [Hmim]Cl solutions: Volumetric and viscometric approach [J].
Brinzei, Mihaela ;
Stefaniu, Amalia ;
Iulian, Olga ;
Ciocirlan, Oana .
JOURNAL OF MOLECULAR LIQUIDS, 2021, 341
[13]   Volumetric and ultrasonic study of polyethylene glycols in aqueous solutions of niacin at different temperatures [J].
Chakraborty, Nabaparna ;
Juglan, K. C. ;
Kumar, Harsh .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2021, 154
[14]   Acoustic and viscosity studies of sodium dodecyl sulfate in aqueous solutions of gelatin [J].
Chauhan, S. ;
Chauhan, M. S. ;
Jyoti, J. ;
Rajni .
JOURNAL OF MOLECULAR LIQUIDS, 2009, 148 (01) :24-28
[15]  
Dey S. K., 2020, Lett. Appl. Nanobiosci, V9, P1547, DOI [10.33263/LIANBS94.15471561, DOI 10.33263/LIANBS94.15471561]
[16]   Analysis of ultraacoustic behavior of L-aspartic acid in aqueous sodium benzoate and ammonium acetate media [J].
Dhal, Kshirabdhitanaya ;
Das, Prasanjit ;
Singh, Sulochana ;
Talukdar, Malabika .
JOURNAL OF MOLECULAR LIQUIDS, 2023, 376
[17]   Ultraacoustic and conductometric studies on the interactions of L-glutamic acid with potassium sorbate and sodium benzoate in aqueous media [J].
Dhal, Kshirabdhitanaya ;
Singh, Sulochana ;
Talukdar, Malabika .
JOURNAL OF MOLECULAR LIQUIDS, 2022, 368
[18]   Volumetric, viscometric and spectroscopic studies of molecular interactions of glutamic acid with potassium sorbate and sodium benzoate in aqueous medium at T=293.15-313.15 K [J].
Dhal, Kshirabdhitanaya ;
Singh, Sulochana ;
Talukdar, Malabika .
JOURNAL OF MOLECULAR LIQUIDS, 2022, 361
[19]   Elucidation of molecular interactions of aspartic acid with aqueous potassium sorbate and sodium benzoate: Volumetric, viscometric and FTIR spectroscopic investigation [J].
Dhal, Kshirabdhitanaya ;
Singh, Sulochana ;
Talukdar, Malabika .
JOURNAL OF MOLECULAR LIQUIDS, 2022, 352
[20]   Volumetric and viscometric studies of some drugs in aqueous solutions at different temperatures [J].
Dhondge, Sudhakar S. ;
Zodape, Sangesh P. ;
Parwate, Dilip V. .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2012, 48 :207-212