Fabrication of Ag-TiO2 nanocomposite employing dielectric barrier discharge plasma for photodegradation of methylene blue

被引:10
作者
Muneeb, Abdul [1 ,2 ]
Rafique, M. Shahid [1 ]
Murtaza, M. Ghulam [1 ]
Arshad, Tehreem [1 ]
Shahadat, Imran [1 ]
Rafique, Maryum [1 ]
Nazir, Aqsa [1 ]
机构
[1] Univ Engn & Technol Lahore, Fac Nat Sci Humanities & Islamic Study, Dept Phys, Lahore 54890, Pakistan
[2] Univ Engn & Technol Lahore, Laser & Optron Ctr, Lahore 54890, Pakistan
关键词
DBD Plasma; Nanocomposites; Photocatalysis; Methylene blue; Ac power supply; Ag-TiO2; PHOTOCATALYTIC ACTIVITY; GREEN SYNTHESIS; TIO2; AG; NANOPARTICLES; NANOMATERIALS; DEGRADATION; TITANIA; UV;
D O I
10.1016/j.physb.2023.414995
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Ag nanoparticles have been incorporated in TiO2 to form Ag-TiO2 nanocomposite. The purpose was to enhance the photocatalytic activity of TiO2 in visible region. Ag-TiO2 nanocomposites were prepared using Dielectric Barrier Discharge Plasma operated at 14, 16 and 20 kV. XRD depicts the formation of cubic Ag with tetragonal geometry of TiO2. FTIR confirms the presence of Ag-O, Ti-O and Ag-O-Ti vibrations. UV-VIS shows that the TiO2 and pristine AgTiO2 do not have any absorption peaks in visible region. However, for 16 and 20 kV plasma treated samples, an absorption peak in visible region (580-720 nm) is observed. Evolution of this peak is because of the bandgap tuning from 3.15 to 2.31 eV. Ag-TiO2 based Photodegradation of methylene blue under UV, Plasma, and sunlight reveals that 16 kV Plasma treated Ag-TiO2 is the best under sunlight (93%). It is concluded that plasma treatment has activated Ag-TiO2 for photo degradation in the visible region.
引用
收藏
页数:10
相关论文
共 61 条
[1]   An Experimental and Theoretical Study on the Effect of Silver Nanoparticles Concentration on the Structural, Morphological, Optical, and Electronic Properties of TiO2 Nanocrystals [J].
Ahmed, Faheem ;
Kanoun, Mohammed Benali ;
Awada, Chawki ;
Jonin, Christian ;
Brevet, Pierre-Francois .
CRYSTALS, 2021, 11 (12)
[2]   Concurrent Synthesis and Immobilization of Ag Nanoparticles over TiO2 via Plasma Reduction for Photocatalytic Treatment of Methyl Blue in Water [J].
Altaf, Noor Ul Huda ;
Naz, Muhammad Yasin ;
Shukrullah, Shazia ;
Ghaffar, Abdul ;
Irfan, Muhammad ;
Walczak, Dominik ;
Glowacz, Adam ;
Mahnashi, Mater H. ;
Rahman, Saifur ;
Krolczyk, Grzegorz ;
Alqarni, Ali O. ;
Niazi, Usama Muhammad .
MATERIALS, 2021, 14 (20)
[3]   Antimicrobial activity of TiO2:Ag nanocrystalline heterostructures: Experimental and theoretical insights [J].
Andre, Rafaela S. ;
Zamperini, Camila A. ;
Mima, Ewerton G. ;
Longo, Valeria M. ;
Albuquerque, Anderson R. ;
Sambrano, Julio R. ;
Machado, Ana L. ;
Vergani, Carlos E. ;
Hernandes, Antonio C. ;
Varela, Jose A. ;
Longo, Elson .
CHEMICAL PHYSICS, 2015, 459 :87-95
[4]   Green biomimetic synthesis of Ag-TiO2 nanocomposite using Origanum majorana leaf extract under sonication and their biological activities [J].
Bhardwaj, Diksha ;
Singh, Ruby .
BIORESOURCES AND BIOPROCESSING, 2021, 8 (01)
[5]  
Bokuniaeva A. O., 2019, Journal of Physics: Conference Series, V1410, DOI 10.1088/1742-6596/1410/1/012057
[6]   Understanding the superior photocatalytic activity of noble metals modified titania under UV and visible light irradiation [J].
Bumajdad, Ali ;
Madkour, Metwally .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (16) :7146-7158
[7]   Photoinduced reactivity of titanium dioxide [J].
Carp, O ;
Huisman, CL ;
Reller, A .
PROGRESS IN SOLID STATE CHEMISTRY, 2004, 32 (1-2) :33-177
[8]   Recent progress on Ag/TiO2 photocatalysts: photocatalytic and bactericidal behaviors [J].
Chakhtouna, Hanane ;
Benzeid, Hanane ;
Zari, Nadia ;
Qaiss, Abou el Kacem ;
Bouhfid, Rachid .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2021, 28 (33) :44638-44666
[9]   Synthesis and Ag-loading-density-dependent photocatalytic activity of Ag@TiO2 hybrid nanocrystals [J].
Chen, Deliang ;
Chen, Qianqian ;
Ge, Lianfang ;
Yin, Li ;
Fan, Bingbing ;
Wang, Hailong ;
Lu, Hongxia ;
Xu, Hongliang ;
Zhang, Rui ;
Shao, Guosheng .
APPLIED SURFACE SCIENCE, 2013, 284 :921-929
[10]   Photocatalytic degradation of organic pollutants using TiO2-based photocatalysts: A review [J].
Chen, Dongjie ;
Cheng, Yanling ;
Zhou, Nan ;
Chen, Paul ;
Wang, Yunpu ;
Li, Kun ;
Huo, Shuhao ;
Cheng, Pengfei ;
Peng, Peng ;
Zhang, Renchuang ;
Wang, Lu ;
Liu, Hui ;
Liu, Yuhuan ;
Ruan, Roger .
JOURNAL OF CLEANER PRODUCTION, 2020, 268