Consumption of petroleum derivatives has triggered extremely negative effects on the environ-ment, to illustrate, global warming. This research is intended to use biodiesel as a fuel in diesel engines, and a water-emulsion technique is proposed. This study considers Pongamia biodiesel fuel blend proportions specifically, B20, B40, B60, B80, and B100 by varying the surfactant rates to 1% and 2%. The emulsions of Pongamia biodiesel and water blends were prepared and named B20W5S2, B40W5S2, B60W5S2, B80W5S2, B100W5S2, and B100W10S2 by varying the surfac-tant rates as 1%, and 2%, and water as 5%,10% and 15% respectively. The biodiesel outcomes and the emission features of the biodiesel in the CI engine were analyzed with the help of a Neural Network (NN). B100W10S2 emulsion involved more specific fuel consumption than all other fuels. In full load conditions, diesel had high Brake Thermal Efficiency (BTE) compared to bio-diesel emulsions whereas B100W5S2 had a low BTE. The BTE of B20W5S2 was 7.14% higher at low-load conditions than that of diesel fuel. B100W5S2 emulsion was observed to emit 47.9% fewer Hydrocarbons (HC) than other blends and emulsions at all load conditions. The carbon monoxide emission was 3.33% at part load conditions and 5% less for full-load conditions in the case of B20W5S2 and B80W5S1 when compared with base fuel (diesel). All emulsions resulted in low NOx emissions compared to diesel. 550 PPM and 10% water contributed to the B100W10S2 emulsion. In this emulsion, 43.74% less NOx was observed compared to all other fuel blends at all load conditions. B20W5S2 emitted 2.88% low smoke in all the load conditions in comparison with diesel fuel.