All-in-one strategy for the nano-engineering of paper-based bifunctional fluorescent platform for robustly-integrated real-time monitoring of food and drinking-water safety

被引:12
作者
Jiang, Huie [1 ,2 ,3 ]
Zhang, Qian [1 ]
Li, Nihao [1 ]
Li, Zhijian [1 ,3 ]
Chen, Lijuan [1 ]
Yang, Fengqian [1 ]
Zhao, Suqiu [1 ]
Liu, Xinhua [2 ,3 ]
机构
[1] Shaanxi Univ Sci & Technol, Minist Educ, Key Lab Auxiliary Chem & Technol Chem Ind, Xian 710021, Shaanxi, Peoples R China
[2] Shaanxi Univ Sci & Technol, Coll Bioresources Chem & Mat Engn, Natl Demonstrat Ctr Expt Light Chem Engn Educ, Xian 710021, Peoples R China
[3] Shaanxi Univ Sci & Technol, Minist Educ, Key Lab Auxiliary Chem & Technol Chem Ind, Xian 710021, Shaanxi, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Paper; Cu2+/H2S; Bifunctional probe; Food spoilage and drinking water safety; Visual monitoring; HYDROGEN-SULFIDE; COPPER; PROBE; SENSOR; SPECTROMETRY;
D O I
10.1016/j.jhazmat.2024.133735
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Cu2+ contamination and food spoilage raise food and drinking water safety issues, posing a serious threat to human health. Besides, Cu2+ and H2S levels indicate excess Cu2+-caused diseases and protein -containing food spoilage. Herein, a coumarin-containing bifunctional paper -based fluorescent platform integrated with a straightforward smartphone color recognition app is developed by an all -in -one strategy. The proposed fluorescent materials can simultaneously detect Cu2+ and H2S for on -demand food and drinking water safety monitoring at home. Specifically, a coumarin-derived fluorescence sensor (referred to as CMIA) with a low detection limit (0.430 mu M) and high -selectivity/ -sensitivity for Cu2+ is synthesized through a simple one-step route and then loaded onto commercially used cellulose fiber filter paper to engineer a biomass -based fluorescent material (CMIA-FP). The CMIA-FP offers user-friendly, high -precision, fast -responsive, and real-time visual monitoring of Cu2+. Moreover, CMIA forms a chemically stable complex with Cu2+, loaded onto filter paper to prepare another biomass -based fluorescent platform (CMIA-CU-FP) for visual real-time monitoring of H2S. Based on the exquisite composition design, the proposed dual -function paper -based fluorescent materials equipped with a smartphone color recognition program concurrently realize fast, accurate, and easy real-time monitoring of Cu2+ in drinking water and H2S in chicken breast -/shrimp -spoilage, demonstrating an effective detection strategy for the Cu2+ and H2S monitoring and presenting the new type of biomass -based platforms for concentrated reflection of drinking water and food safety.
引用
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页数:11
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