Co(OAc)2/TBHP as a Highly Active Catalytic System for the Selective Oxidation of Aromatic Amines to Nitro Derivatives

被引：3
|
作者：
Wu, Liqiong [1 ,2 ]
Yao, Lifeng [3 ]
Yin, Weiyan [1 ,2 ,4 ]
Yu, Junxia [1 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430074, Peoples R China
[2] Wuhan Text Univ, Sch Chem & Chem Engn, Wuhan 430073, Peoples R China
[3] Jiangxi Sci & Technol Normal Univ, Sch Chem & Chem Engn, Nanchang 330013, Peoples R China
[4] Wuhan Univ Sci & Technol, State Environm Protect Key Lab Mineral Metallurg R, Wuhan 430081, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2023年 / 55卷 / 19期
基金：
中国国家自然科学基金;
关键词：
Co(OAc)(2)center dot 4H(2)O; tert-butyl hydroperoxide; ligand-free; selective oxidation; aromatic amines; NITROCOMPOUNDS; COMPLEXES; NITRATION;
D O I：
10.1055/a-2110-8622
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient cobalt-catalyzed protocol for the selective oxidation of anilines using a combination of inexpensive tert-butyl hydroperoxide and Co(OAc)(2)center dot 4H(2)O without any ligand has been developed, providing the nitroarene products in good to excellent yields (up to 96%).
引用
收藏
页码：3104 / 3108
页数：5
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