Ru(phen)3Cl2-Catalyzed Chlorotrifluoromethylation of Unactivated Alkenes

被引：1

作者：

Su, Wenhao ^{[1
]}

Cui, Jing ^{[1
]}

Zeng, Runsheng ^{[1
]}

机构：

[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

来源：

CHEMISTRYOPEN | 2023年 / 12卷 / 07期

关键词：

ruthenium catalysis; chlorotrifluoromethylation; alkyl halides; unactivated alkenes; bifunctionalization; TRIFLUOROMETHYLATION; EFFICIENT; FLUORINE; OXYTRIFLUOROMETHYLATION; CHLORIDES; CF3SO2NA; OLEFINS;

D O I：

10.1002/open.202300068

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel Ru(phen)(3)Cl-2-catalyzed free-radical chlorotrifluoromethylation reaction of unactivated olefins was investigated. Substituted 8-aminoquinoline-derived inert enamides were reacted with the Togni regent to afford a broad range of Cl-containing trifluoromethyl derivatives in good yields. The reaction proceeded at 90 & DEG;C and experimental result shows that the chlorine source of the products originated from LiCl.

引用

页数：5

共 53 条

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