Catalytic pyrolysis of Paulownia wood and bio-oil characterization

被引:1
作者
Yildiz, Derya [1 ]
Yorgun, Sait [1 ]
机构
[1] Eskisehir Osmangazi Univ, Chem Engn Dept, Eskisehir, Turkiye
关键词
Catalytic pyrolysis; catalyst; ZSM-5; Na2CO3; sepiolite; RENEWABLE ENERGY-SOURCES; BIOMASS PYROLYSIS; AUGER REACTOR; HEATING VALUES; PRODUCT YIELDS; PINE WOOD; L; TEMPERATURE; SAWDUST; LIGNIN;
D O I
10.1080/15567036.2023.2289563
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This study focused on the catalytic pyrolysis of Paulownia (P. elongota) wood. The effects of ZSM-5, Na2CO3, sepiolite, and catalyst ratio (10-80% by wood weight) on product yields and bio-oil composition were investigated. In pyrolysis experiments, 500 degrees C pyrolysis temperature, 50 degrees C min(-1) heating rate, and 100 mL min(-1) N-2 flow rate were kept as constant. The catalyst type and catalyst ratio changed the product yields and bio-oil compositions. Pyrolysis conversion was increased for all catalyst types. Maximum liquid product yields were obtained as 63.26 wt%, 56.18 wt%, and 54.59 wt% with the ZSM-5, Na2CO3 and sepiolite, respectively, at 10 wt% catalyst ratio. For all catalysts, it was determined that the liquid and solid yields reduce and the gas product yield rises with the catalyst ratio. The bio-oil characterization was performed with elemental analysis, FTIR, (HNMR)-H-1, and GC-MS techniques. The bio-oil composition was determined to consist of alkanes, carboxylic acids, ketones, esters, benzenes, and phenols.
引用
收藏
页码:1626 / 1643
页数:18
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