Synthesis of CuO and Cu2O nanoparticles stabilized on the magnetic Fe3O4-Montmorillonite-K10 and comparison of their catalytic activity in A3 coupling reaction

被引：10
作者：
Bagheri, Fatemeh Hassani [1 ]
Khabazzadeh, Hojatollah [1 ]
Fayazi, Maryam [2 ]
Rezaeipour, Marjan [1 ]
机构：
[1] Shahid Bahonar Univ Kerman, Dept Chem, Kerman 7616914111, Iran
[2] Grad Univ Adv Technol, Inst Sci & High Technol & Environm Sci, Dept Environm, Kerman 7631818356, Iran
来源：
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2023年 / 20卷 / 06期
关键词：
A(3) coupling reaction; Cupric oxide; Cuprous oxide; Heterogeneous nanocatalysts; Montmorillonite-K10; ACID-ACTIVATED MONTMORILLONITE; ONE-POT SYNTHESIS; MULTICOMPONENT REACTIONS; REUSABLE CATALYST; EFFICIENT; COPPER; PROPARGYLAMINES; AMINE; CLAY;
D O I：
10.1007/s13738-023-02768-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
CuO and Cu2O nanoparticles were prepared by a green method at room temperature and then employed for the synthesis of montmorillonite-K10/iron oxide/cupric oxide (MMT-K10/Fe3O4/CuO) and montmorillonite-K10/iron oxide/cuprous oxide (MMT-K10/Fe3O4/Cu2O) nanocatalysts. The properties of these nanocatalysts were explored using Fourier transformed infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), vibrating-sample magnetometer (VSM), and inductively coupled plasma (ICP). The catalytic activity of these heterogeneous nanocatalysts was investigated in the A(3)-coupling reaction for the synthesis of propargylamines. The results revealed that the highest efficiency was related to MMT-K10/Fe3O4/CuO nanocatalyst at 80 & DEG;C in toluene solvent. Moreover, the separation and recovery of the nanocatalysts were straightforward, efficient, and cost-effective.[GRAPIHCS]
引用
收藏
页码：1439 / 1456
页数：18
相关论文
共 45 条
  • [1] Choline chloride-urea deep eutectic solvent as an efficient media for the synthesis of propargylamines via organocuprate intermediate
    Abtahi, Bahareh
    Tavakol, Hossein
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2020, 34 (11)
  • [2] Arend M., 1998, ANGEW CHEM, V110, P1096, DOI DOI 10.1002/(SICI)1521-3757(19980420)110:8
  • [3] Natural bentonite clay/dilute HNO3 (40%) -: A mild, efficient, and reusable catalyst/reagent system for selective mono nitration and benzylic oxidations
    Bahulayan, D
    Narayan, G
    Sreekumar, V
    Lalithambika, M
    [J]. SYNTHETIC COMMUNICATIONS, 2002, 32 (23) : 3565 - 3574
  • [4] Room Temperature Synthesis of Copper Oxide Nanoparticles: Morphological Evaluation and Their Catalytic Applications for Degradation of Dyes and C-N Bond Formation Reaction
    Bhosale, Manohar A.
    Karekar, Supriya C.
    Bhanage, Bhalchandra M.
    [J]. CHEMISTRYSELECT, 2016, 1 (19): : 6297 - 6307
  • [5] A simple approach for sonochemical synthesis of Cu2O nanoparticles with high catalytic properties
    Bhosale, Manohar A.
    Bhanage, Bhalchandra M.
    [J]. ADVANCED POWDER TECHNOLOGY, 2016, 27 (01) : 238 - 244
  • [6] Single and double A3-coupling (aldehyde-amine-alkyne) reaction catalyzed by an air stable copper(I)-phosphole complex
    Cammarata, Jose Ricardo
    Rivera, Rocio
    Fuentes, Franmerly
    Otero, Yomaira
    Ocando-Mavarez, Edgar
    Arce, Alejandro
    Garcia, Juan M.
    [J]. TETRAHEDRON LETTERS, 2017, 58 (43) : 4078 - 4081
  • [7] ENVIRONMENTALLY FRIENDLY CHEMISTRY USING SUPPORTED REAGENT CATALYSTS - STRUCTURE-PROPERTY RELATIONSHIPS FOR CLAYZIC
    CLARK, JH
    CULLEN, SR
    BARLOW, SJ
    BASTOCK, TW
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (06): : 1117 - 1130
  • [8] Covalently immobilized indium(III) composite (In/SiO2) as highly efficient reusable catalyst for A3-coupling of aldehydes, alkynes and amines under solvent-free conditions
    da Silva, Tiago Lima
    Rambo, Raoni Scheibler
    Rampon, Daniel da Silveira
    Radatz, Catia Schwartz
    Benvenutti, Edilson Valmir
    Russowsky, Dennis
    Schneider, Paulo Henrique
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2015, 399 : 71 - 78
  • [9] PRECONCENTRATION OF Cr(III) AND SPECIATION ANALYSIS OF CHROMIUM EMPLOYING MONTMORILLONITE SATURATED WITH POTASSIUM IONS
    Frois, Sergio Ribeiro
    Grassi, Marco Tadeu
    Fernandes, Tatyane Caruso
    dos Santos Barreto, Ronaldo Adriano
    Abate, Gilberto
    [J]. QUIMICA NOVA, 2011, 34 (03): : 462 - 467
  • [10] Strategies for Innovation in Multicomponent Reaction Design
    Ganem, Bruce
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (03) : 463 - 472
12345