A Family of Cagelike Mn-Silsesquioxane/Bathophenanthroline Complexes: Synthesis, Structure, and Catalytic and Antifungal Activity

被引：10

作者：

Bilyachenko, Alexey N. ^{[1
,2
]}

Gutsul, Evgenii I. ^{[1
]}

Khrustalev, Victor N. ^{[2
,3
]}

Chusova, Olga ^{[1
]}

Dorovatovskii, Pavel V. ^{[4
]}

Aliyeva, Vusala A. ^{[5
,6
]}

Paninho, Ana B. ^{[6
]}

Nunes, Ana V. M. ^{[6
]}

Mahmudov, Kamran T. ^{[5
,7
]}

Shubina, Elena S. ^{[1
]}

Pombeiro, Armando J. L. ^{[2
,5
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] Peoples Friendship Univ Russia, Moscow 117198, Russia

[3] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia

[4] Kurchatov Inst, Natl Res Ctr, Moscow 123182, Russia

[5] Univ Lisbon, Inst Mol Sci, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal

[6] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, LAQV REQUIMTE, P-2829516 Caparica, Portugal

[7] Baku State Univ, Excellence Ctr, Baku 1148, Azerbaijan

来源：

INORGANIC CHEMISTRY | 2023年 / 62卷 / 38期

基金：

俄罗斯科学基金会;

关键词：

POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; N-LIGANDS SYNTHESIS; EFFICIENT CATALYSTS; CARBON-DIOXIDE; CO2; METALLASILSESQUIOXANES; MANGANESE; EPOXIDES; METALLOSILOXANES; CYCLOADDITION;

D O I：

10.1021/acs.inorgchem.3c02040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This study reports a novel family of cage manganesesilsesquioxanes prepared via complexation with bathophenanthroline (4,7-diphenyl-1,10-phenanthroline). The resulting Mn-4-, Mn6Li2-, and Mn4Na-compounds exhibit several unprecedented cage metallasilsesquioxane structural features, including intriguing self-assembly of silsesquioxane ligands. Complexes were tested in vitro for fungicidal activity against seven classes of phytopathogenic fungi. The representative Mn4Na-complex acts as a catalyst in the cycloaddition of CO2 to epoxides under solvent-free conditions to form cyclic carbonates in good yields.

引用

页码：15537 / 15549

页数：13

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